18141-27-0

Basic information

• Product Name: Silane, trichloro(phenylmethoxy)-
• CAS NO: 18141-27-0
• Molecular Formula: C7H7Cl3OSi
• Molecular Weight: 241.576
• Mol File: 18141-27-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, trichloro(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trichloro(phenylmethoxy)-(18141-27-0)
• EPA Substance Registry System: Silane, trichloro(phenylmethoxy)-(18141-27-0)

Safety Data

• Hazardous Substances Data: 18141-27-0(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 3613-53-4 1-((benzyloxy)methyl)-4-methoxybenzene 

Downstream Products

• 144-79-6 chloromethyldiphenylsilane 
• 138213-51-1 3,3-dichloro-1-methyl-1,1-diphenyldisiloxane 
• 138193-49-4 1,1,1-trichloromethyldiphenyldisiloxane 
• 108-88-3 toluene 
• 75-79-6 Methyltrichlorosilane 
• 100-44-7 benzyl chloride 
• 138193-45-0 1,1,1,3-tetrachloro-3-methyldisiloxane 
• 138193-44-9 1,1,3,3-tetrachloro-1-methyldisiloxane 
• 115147-29-0 pentachloromethyldisiloxane 
• 588-59-0 stilbene 
• 2632-77-1 1,1,1,3-tetrachloro-3,3-dimethyldisiloxane 
• 138193-41-6 1,3,3-trichloro-1,1-dimethylsiloxane 
• 138193-42-7 C₂H₇Cl₅O₂Si₃ 
• 75-78-5 dimethylsilicon dichloride 

Relevant articles and documents

α-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride

α-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.