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18159-55-2

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18159-55-2 Usage

General Description

TRI-T-BUTYLSILANE, also known as TTBS, is a chemical compound with the molecular formula C12H28Si. It is a colorless, flammable liquid with a strong characteristic odor. TRI-T-BUTYLSILANE is primarily used as a reducing agent in organic synthesis, and as a precursor for the introduction of silicon into organic molecules. It is also utilized as a protective group for alcohols and a reagent for the deprotection of silyl ethers. Additionally, it is employed in the production of silicon-based materials and as a component in the manufacture of electronic devices and other high-technology products. Due to its potentially hazardous nature, TRI-T-BUTYLSILANE requires careful handling and storage to minimize the risk of fire and environmental contamination.

Check Digit Verification of cas no

The CAS Registry Mumber 18159-55-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,1,5 and 9 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 18159-55:
(7*1)+(6*8)+(5*1)+(4*5)+(3*9)+(2*5)+(1*5)=122
122 % 10 = 2
So 18159-55-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H28Si/c1-10(2,3)13(11(4,5)6)12(7,8)9/h13H,1-9H3

18159-55-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name tritert-butylsilicon

1.2 Other means of identification

Product number -
Other names TRI-TERT-BUTYLSILANE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18159-55-2 SDS

18159-55-2Relevant articles and documents

Dexheimer,Spialter

, p. 1771 (1975)

Dexheimer et al.

, p. 21,26 (1975)

Isoelectronic caesium compounds: The triphosphenide Cs[tBu 3SiPPPSitBu3] and the enolate Cs[OCH=CH2]

Lerner, Hans-Wolfram,Saenger, Inge,Schoedel, Frauke,Lorbach, Andreas,Bolte, Michael,Wagner, Matthias

, p. 787 - 792 (2008/09/20)

The caesium triphosphenide Cs[tBu3SiPPPSitBu3] was accessible from the reaction of CsF with the sodium triphosphenide Na[tBu 3SiPPPSitBu3] in tetrahydrofuran at room temperature. In contrast to the preparation of tetrahydrofuran-solvated silanides M[SitBu 3] (M = Li, Na, K), our efforts to synthesize the caesium silanide Cs[SitBu3] as a tetrahydrofuran complex failed. When tBu 3SiBr was treated with an excess of caesium metal in tetrahydrofuran at room temperature, the caesium enolate Cs[OCH=CH2] and the supersilane tBu3SiH formed rather than the silanide Cs[SitBu 3]. X-Ray quality crystals of the enolate Cs[OCH=CH2] (orthorhombic, Pnma) were obtained from tetrahydrofuran at ambient temperature. In contrast to the structures of its homologues M[tBu3SiPPPSitBu 3] (M = Na, K), the caesium triphosphenide Cs[tBu 3SiPPPSitBu3] features a polymer in the solid state (orthorhombic, Cmcm). The Royal Society of Chemistry.

Tri-tert-butylsilyl(triisopropylsilyl)silylene (tBu)3Si-Si-Si(iPr)3 and chemical evidence for its reactions from a triplet electronic state [15]

Jiang,Gaspar

, p. 8622 - 8623 (2007/10/03)

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