Welcome to LookChem.com Sign In|Join Free

Cas Database

1825-61-2

1825-61-2

Identification

Synonyms:LS 510;Methoxytrimethylsilane;Methyl trimethylsilyl ether;NSC 139858;SS 2010;TSL8111;Trimethylsilyl methyl ether;Z 6013;

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS view more

  • Pictogram(s):IrritantXi, FlammableF

  • Hazard Codes:F,Xi

  • Signal Word:No signal word.

  • Hazard Statement:none

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TRC
  • Product Description:Methoxytrimethylsilane
  • Packaging:50g
  • Price:$ 45
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:Methoxytrimethylsilane >98.0%(GC)
  • Packaging:25mL
  • Price:$ 36
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:Methoxytrimethylsilane >98.0%(GC)
  • Packaging:250mL
  • Price:$ 176
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Methoxytrimethylsilane 99%
  • Packaging:250g
  • Price:$ 510
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Methoxytrimethylsilane 99%
  • Packaging:100g
  • Price:$ 240
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Methoxytrimethylsilane 99%
  • Packaging:25g
  • Price:$ 92.2
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Oakwood
  • Product Description:Methoxytrimethylsilane
  • Packaging:2.5Kg
  • Price:$ 360
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Oakwood
  • Product Description:Methoxytrimethylsilane
  • Packaging:25g
  • Price:$ 15
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Oakwood
  • Product Description:Methoxytrimethylsilane
  • Packaging:100g
  • Price:$ 40
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Oakwood
  • Product Description:Methoxytrimethylsilane
  • Packaging:500g
  • Price:$ 90
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 113 Articles be found

Owsley et al.

, p. 295 (1979)

Boron Compounds; LV. A New O-Silylation Method via Diethylboryl Ethers and Esters

Taba, Kalulu M.,Dahlhoff, Wilhelm Volker

, p. 652 - 653 (1982)

-

UNUSUAL CYCLIZATION OF TRIMETHYLSILYL DERIVATIVE OF TRISACETYLHYDRAZINE

Kalinin, A. V.,Khasapov, B. N.,Apasov, E. T.,Kalikhman, I. D.,Ioffe, S. L.

, p. 644 - 646 (1984)

-

The Thermal Elimination of Ketene from Alkyl Trimethylsilylacetates

Taylor, Roger

, p. 741 - 742 (1987)

Alkyl trimethylsilylacetates readily undergo thermal elimination to give ketene and trimethylsilyl alkyl ethers; Arrhenius data have been obtained for this new unimolecular first-order reaction which involves a semi-concerted four-centre process.

CO Reduction to CH3OSiMe3: Electrophile-Promoted Hydride Migration at a Single Fe Site

Deegan, Meaghan M.,Peters, Jonas C.

, p. 2561 - 2564 (2017)

One of the major challenges associated with developing molecular Fischer-Tropsch catalysts is the design of systems that promote the formation of C-H bonds from H2 and CO while also facilitating the release of the resulting CO-derived organic products. To this end, we describe the synthesis of reduced iron-hydride/carbonyl complexes that enable an electrophile-promoted hydride migration process, resulting in the reduction of coordinated CO to a siloxymethyl (LnFe-CH2OSiMe3) group. Intramolecular hydride-to-CO migrations are extremely rare, and to our knowledge the system described herein is the first example where such a process can be accessed from a thermally stable M(CO)(H) complex. Further addition of H2 to LnFe-CH2OSiMe3 releases CH3OSiMe3, demonstrating net four-electron reduction of CO to CH3OSiMe3 at a single Fe site.

Trifluormethansulfinsaeure-Azid und Trifluormethan-Schwefeloxidnitrid - Synthese und chemische Eigenschaften

Bechtold, Thomas,Eingelbrecht, Alfred

, p. 379 - 402 (1982)

The synthesis of a perfluoroalkyl derivative of sulfanuric acid was attempted via the thermal decomposition of a) F3CSO2NPCl3 to yield OPCl3 as a byproduct, b) F3CSON3 to give the desired product by splitting off elemental nitrogen.However F3CSO2NPCl3 unexpectedly is stable up to 500 deg, when it looses mainly the F3C-group.Trifluoromethane sulfinic acidazide, F3CSON3, which we synthesised from the acid chloride and NaN3 at -40 deg starts to decompose as expected around -10 deg forming as the primary intermediate F3CSON, which can be formulated containing a S-N triple bond, and which proved to be extremely reactive.This trifluoromethan-sulfur oxide nitride oligomerizes spontaneously, or in presence of suitable compounds can be captured to yield various new compounds.With acetonitril a dithiatriazin is formed, with F3CSON3 an explosive sulfonimidoyl-azide, with trimethylsilyl azide, N-trimethylsilyl-trifluoromethan-sulfonimidoyl chloride.F3CSOCl yields an N-substituted sulfonimidoyl chloride in two diastereomeric forms.

The synthesis and rearrangement of cis-M(CO)4(PPh3)CH2I (M = Mn, Re)

Mandal, Santosh K.,Ho, Douglas M.,Orchin, Milton

, p. 313 - 331 (1990)

Manganese and rhenium iodomethyl complexes, cis-M(CO)4(PPh3)CH2I (1a, M = Mn; 1b, M = Re) have been prepared by treating the corresponding methoxymethyl complexes, cis-M(CO)4(PPh3)CH2OCH3 (2a, M = Mn; 2b, M = Re) with (CH3)3SiI.The attempted alternate syn

Preparation of organic/inorganic hybrid hollow particles based on gelation of polymer vesicles

Du, Jianzhong,Chen, Yongming

, p. 5710 - 5716 (2004)

In a previous communication, we have reported the study of novel organic/inorganic hollow particles based on a reactive amphiphilic diblock copolymer, poly(ethylene oxide)-block-poly[3-(trimethoxysilyl)propyl methacrylate] (PEO-b-PTMSPMA). The preparation

A Simple Post-Polymerization Modification Method for Controlling Side-Chain Information in Digital Polymers

K?nig, Niklas Felix,Al Ouahabi, Abdelaziz,Poyer, Salomé,Charles, Laurence,Lutz, Jean-Fran?ois

, p. 7297 - 7301 (2017)

A three-step post-polymerization modification method was developed for the design of digitally encoded poly(phosphodiester)s with controllable side groups. Sequence-defined precursors were synthesized, either manually on polystyrene resins or automaticall

SILICON-CARBON UNSATURATED COMPOUNDS XVII. PHOTOCHEMICAL BEHAVIOR OF 1-METHYL-1-(TRIMETHYLSILYL)DIBENZOSILOLE AND 1-PHENYL-1-(TRIMETHYLSILYL)DIBENZOSILOLE

Ishikawa, Mitsuo,Tabohashi, Tatsuru,Kumada, Makoto,Iyoda, Jun

, p. 79 - 86 (1984)

The photolysis of 1-methyl-1-(trimethylsilyl)dibenzosilole (I) and 1-phenyl-1-(trimethylsilyl)dibenzosilole (II) has been investigated.Irradiation of I in the presence of acetone afforded 1-isopropoxy-1-methyl-2-(trimethylsilyl)dibenzosilole (III), while

FLASH PYROLYSIS: A ROUTE TO "α-KETENIC ESTERS".

Jullien, J.,Pechine, J. M.,Perez, F.

, p. 5525 - 5526 (1983)

3-Oxo 2-propenoic acid methyl ester has been prepared by flash vacuum pyrolysis and characterized by mass spectrometry and chemical trapping.Its four-membered cyclic dimers have been isolated.

The use of phosphorus pentafluoride as a fluorinating agent in organosilicon chemistry. III. Synthesis and characterization of some new fluorosiloxanes

Kifer, Edward W.,Van Dyke, Charles H.

, p. 404 - 408 (1972)

Although the silicon-oxygen bond of siloxanes and alkoxysilanes is readily cleaved by phosphorus pentafluoride, the silicon-hydrogen bond of hydrosiloxanes can be easily fluorinated at low temperatures by this reagent thus providing a convenient source of fluorosiloxanes. The synthesis and characterization of FSiH2OSiH3, (FSiH2)2O, F(CH3)HSiOSiH2CH3, and [F(CH3)HSi]2O are described.

Contributions to the chemistry of halosilane adducts XVIII. On the nature of compounds of trimethylhalosilanes with 1,1,3,3-tetramethylguanidine and 2-trimethylsilyl-1,1,3,3-tetramethylguanidine: preparation and characterization of mono- and bis-(2-trimet

Chaudhry, Subhash C.,Kummer, Dieter

, p. 241 - 252 (1988)

1,1,3,3-Tetramethylguanidine (TMG) and 2-(trimethylsilyl)-1,1,3,3-tetramethyl-guanidine (TMSTMG) react with trimethylhalosilanes Me3SiHal in equimolar ratio with ionization of the Si-halogen bond to give the stable guanidinium salts Hal (

Kondo, T.,Yamamoto, K.,Kumada, M.

, p. 303 - 310 (1973)

Novel 10-I-3 hypervalent iodine-based compounds for electrophilic trifluoromethylation

Eisenberger, Patrick,Gischig, Sebastian,Togni, Antonio

, p. 2579 - 2586 (2006)

The synthesis of a new family of 10-I-3 hypervalent iodine compounds is described in which the CF3 functionality participates directly in the hypervalent bond. These materials are accessible by nucleophilic ligand substitution at iodine using Me3SiCF3 in the presence of a substoichiometric amount of fluoride. The expected T-shaped geometry at iodine was verified by X-ray crystallographic analyses of three of the products (1-trifluoromethyl-1,2-benziodoxol-3-(1 H)-one and two substituted 1-trifluoromethyl-1,3-dihydro-1,2-benziodoxoles). Preliminary results for the direct electrophilic transfer of the trifluoromethyl moiety onto organic nucleophiles show modest reactivity in polar aprotic solvents under relatively mild conditions. The overall process can be understood as a formal umpolung of the CF3 group.

Enantioselective Synthesis of α-Aryl-β2-Amino-Esters by Cooperative Isothiourea and Br?nsted Acid Catalysis

Zhao, Feng,Shu, Chang,Young, Claire M.,Carpenter-Warren, Cameron,Slawin, Alexandra M. Z.,Smith, Andrew D.

supporting information, p. 11892 - 11900 (2021/04/28)

The synthesis of α-aryl-β2-amino esters through enantioselective aminomethylation of an arylacetic acid ester in high yields and enantioselectivity via cooperative isothiourea and Br?nsted acid catalysis is demonstrated. The scope and limitatio

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

Cantat, Thibault,Chauvier, Clément,Imberdis, Arnaud,Thuéry, Pierre

supporting information, p. 14019 - 14023 (2020/06/09)

A novel strategy to prepare methanol from formic acid without an external reductant is presented. The overall process described herein consists of the disproportionation of silyl formates to methoxysilanes, catalyzed by ruthenium complexes, and the production of methanol by simple hydrolysis. Aqueous solutions of MeOH (>1 mL, >70 percent yield) were prepared in this manner. The sustainability of the reaction has been established by recycling of the silicon-containing by-products with inexpensive, readily available, and environmentally benign reagents.

METHOD FOR PREPARING ALKYLALKOXYSILANES

-

Paragraph 0037, (2020/03/29)

A method is useful for preparing alkylalkoxysilanes, such as alkylalkoxysilanes, particularly dimethyldimethoxysilane. The method includes heating at a temperature of 150°C to 400°C, ingredients including an alkyl ether and carbon dioxide, and a source of silicon and catalyst. The carbon dioxide eliminates the need to add halogenated compounds during the method.

A methoxy trimethyl silane alcoholysis process (by machine translation)

-

Paragraph 0007; 0008; 0009, (2017/04/22)

The invention relates to the field of chemical industry, in particular a methoxy trimethyl silane alcoholysis process. The invention is by the reaction tower at the top end of trimethylchlorosilane to enter the reaction vessel, the bottom of the methanol

Process route upstream and downstream products

Process route

pyridine
110-86-1

pyridine

methanol
67-56-1

methanol

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
reagiert analog mit Aethanol und mit Butanol-(1);
methanol
67-56-1

methanol

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With urea; at 20 ℃; for 4h;
88.1%
With triethylamine; at 20 ℃; for 0.05h; Inert atmosphere;
85%
With aniline; 1.) 20 deg C, 15 min, 2.) boiling water bath, 20 min;
23%
With magnesium;
With pyridine; toluene;
With pyridine;
With pyridine; In dichloromethane; for 19h; Ambient temperature;
With triethylamine;
With iron(III) chloride; Methyltrimethoxysilan; at 60 - 75 ℃; Temperature; Autoclave;
With triethylamine; In diethyl ether;
methanol
67-56-1

methanol

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With potassium hydroxide;
methanol
67-56-1

methanol

decamethyltetrasiloxane
141-62-8

decamethyltetrasiloxane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With potassium hydroxide;
methanol
67-56-1

methanol

N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
tetramethylorthosilicate
681-84-5

tetramethylorthosilicate

methylmagnesium chloride
676-58-4

methylmagnesium chloride

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With diethyl ether;
methanol
67-56-1

methanol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
1,1,1,3,3,3-hexamethyl-disilazane; With C12H24KO6(1+)*Br3H(1-); In acetonitrile; at 20 ℃; for 0.0166667h;
methanol; In acetonitrile; at 20 ℃; for 0.333333h;
90%
for 48h; Heating;
methanol
67-56-1

methanol

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With potassium hydroxide;
1,1-dimethylsilacyclobutane
2295-12-7

1,1-dimethylsilacyclobutane

methanol
67-56-1

methanol

1,1,3,3-tetramethyl-1,3-disiletane
1627-98-1

1,1,3,3-tetramethyl-1,3-disiletane

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Conditions
Conditions Yield
With sulfur(VI) hexafluoride; Product distribution; Kinetics; Irradiation;
1,1-dimethylsilacyclobutane
2295-12-7

1,1-dimethylsilacyclobutane

methanol
67-56-1

methanol

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

(methoxydimethylsilyl)(trimethylsilyl)methane
5180-93-8

(methoxydimethylsilyl)(trimethylsilyl)methane

Conditions
Conditions Yield
at 407.9 ℃; Product distribution;

Global suppliers and manufacturers

Global( 75) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Simagchem Corporation
  • Business Type:Manufacturers
  • Contact Tel:+86-592-2680277
  • Emails:sale@simagchem.com
  • Main Products:110
  • Country:China (Mainland)
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Shaanxi BLOOM TECH Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-29-86470566
  • Emails:sales@bloomtechz.com
  • Main Products:79
  • Country:China (Mainland)
  • Shanghai Upbio Tech Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-21-52196435
  • Emails:upbiocn@hotmail.com
  • Main Products:88
  • Country:China (Mainland)
  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
  • Contact Tel:021-51086038
  • Emails:sales@chemwill.com
  • Main Products:56
  • Country:China (Mainland)
  • Siwei Development Group Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-82881840
  • Emails:marksiwei@vip.163.com
  • Main Products:55
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1825-61-2
Post Buying Request Now
close
Remarks: The blank with*must be completed