18267-08-8 Usage
Uses
Used in Chemical Synthesis Industry:
Zirconium(IV) ethoxide is used as a precursor for the synthesis of olefin-functionalized zirconium-containing monomers. These monomers are essential in the production of advanced materials with specific properties, such as high thermal stability and unique catalytic activity.
Used in Coatings and Surface Treatments:
Due to its ability to form stable complexes with various organic and inorganic compounds, zirconium(IV) ethoxide is used in the development of coatings and surface treatments. These coatings can provide enhanced properties such as corrosion resistance, wear resistance, and improved adhesion to various substrates.
Used in Catalysts and Catalyst Support:
Zirconium(IV) ethoxide is utilized in the preparation of catalysts and catalyst supports due to its high surface area and ability to form stable metal-organic frameworks. These catalysts are employed in various chemical reactions, including hydrogenation, polymerization, and oxidation processes.
Used in Ceramics and Glass Industry:
The unique properties of zirconium(IV) ethoxide make it suitable for use in the ceramics and glass industry. It is used as a raw material for the production of advanced ceramics, glass-ceramics, and specialty glasses with improved mechanical, thermal, and optical properties.
Used in Nanotechnology and Materials Science:
Zirconium(IV) ethoxide plays a crucial role in nanotechnology and materials science, where it is used for the synthesis of zirconium-based nanoparticles, nanowires, and other nanostructures. These nanomaterials have potential applications in electronics, energy storage, and sensing devices.
Check Digit Verification of cas no
The CAS Registry Mumber 18267-08-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,2,6 and 7 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 18267-08:
(7*1)+(6*8)+(5*2)+(4*6)+(3*7)+(2*0)+(1*8)=118
118 % 10 = 8
So 18267-08-8 is a valid CAS Registry Number.
InChI:InChI=1/4C2H5O.Zr/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
18267-08-8Relevant articles and documents
The alkoxides of zirconium and hafnium: direct electrochemical synthesis and mass-spectral study. Do ''M(OR)4'', where M = Zr, Hf, Sn really exist?
Turevskaya, E. P.,Kozlova, N. I.,Turova, N. Ya.,Belokon, A. I.,Berdyev, D. V.,et al.
, p. 734 - 742 (2007/10/02)
The direct electrochemical synthesis of zirconium (1a) and hafnium (1b) alkoxides, M(OPri)4*PriOH, Zr(OBui)4'BuiOH (4a) and M(OR)4, where R = Et (2a,b), n-Bu (3a), s-Bu (5a), C2H4OMe (6a,b) has been carried out by anodic oxidation of metals in anhydrous alcohols in the presence of LiCl as a conductive additive to give quantitative yields.The solubility polytherms and dissociation pressure of 1a,b have been investigated.It has been proved by means of chemical analysis, X-ray powder, and IR spectral studies that the desolvation of 1a,b and Sn(OPri)4*PriOH (1c) is accompanied by the formation of amorphous oxocompounds M3O(OPri)10.On the basis of 1H NMR data it has been proved that the structure of the latter is analogous to that of known triangular cluster molecules M3(μ3-O)(μ3-OR)(OR)6, where M = Mo, W, U.Mass-spectral data and the determined physicochemical characteristics of 1-5 permit to conclude that the samples of composition M(OR)4, where M = Zr, Hf, and 2, 3, 5 contain tri- and tetranuclear oxocomplexes M3O(OR)10 and M4O(OR)14 respectively, along with Zr(OR)4 oligomers of different molecular complexity. - Key words: oxoalkoxides, zirconium and hafnium alkoxides, electrochemical synthesis, mass-spectra, IR-, NMR-spectral, X-ray powder analysis.