18402-43-2

Basic information

• Product Name: Benzeneacetic acid, triethylsilyl ester
• CAS NO: 18402-43-2
• Molecular Formula: C14H22O2Si
• Molecular Weight: 250.413
• Mol File: 18402-43-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, triethylsilyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, triethylsilyl ester(18402-43-2)
• EPA Substance Registry System: Benzeneacetic acid, triethylsilyl ester(18402-43-2)

Safety Data

• Hazardous Substances Data: 18402-43-2(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 103-82-2 phenylacetic acid 
• 101-97-3 Ethyl 2-phenylethanoate 

Downstream Products

• 33415-47-3 (2,2-Bis-triethylsilanyloxy-vinyl)-benzene 

Relevant articles and documents

Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters

Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh3), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.

Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters

Tris(triphenylphosphine)cuprous chloride [Cu(PPh3)3Cl] has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% Cu(PPh3)3Cl, dehydrosilylation reactions in acetonitrile afforded the corresponding silyl esters at 80°C in good yields. It was noted that triphenylphosphine itself also functions as an adequate catalyst for the reaction. Copyright Taylor & Francis Group, LLC.