18407-16-4Relevant articles and documents
Silylation of silanols with vinylsilanes catalyzed by a ruthenium complex
Marciniec, Bogdan,Pawlu?, Piotr,Hreczycho, Grzegorz,Macina, Anna,Madalska, Martyna
, p. 1310 - 1313 (2008/09/18)
A new ruthenium complex-catalyzed O-silylation of silanols with vinylsilanes leading to siloxane bond formation with the evolution of ethylene is described. A maximum conversion of silanol is reached using an excess of vinylsilane to also yield the product of the homo-coupling of the latter. Under the optimum conditions, when vinylsilane with at least one ethoxy substituent is used, the reaction gives exclusively unsymmetrical siloxanes.
REACTIVITIES OF CHLORINATED ORGANOPOLYSILANES IN OXIDATION AND NUCLEOPHILIC SUBSTITUTION
Semenov, V. V.,Brevnova, T. N.,Khorshev, S. Ya.
, p. 1881 - 1887 (2007/10/02)
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