18407-91-5Relevant articles and documents
The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones
Chen, Qiang,Tanaka, Shinya,Fujita, Takeshi,Chen, Luyang,Minato, Taketoshi,Ishikawa, Yoshifumi,Chen, Mingwei,Asao, Naoki,Yamamoto, Yoshinori,Jin, Tienan
supporting information, p. 3344 - 3346 (2014/03/21)
The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy. The Royal Society of Chemistry 2014.
Trimethylstannylvinyl cuprates - - generation and 1, 4- conjugate addition to α,β - unsaturated ketones
Pereira, Oswy Z.,Chan T
, p. 8749 - 8752 (2007/10/02)
A new convenient route to the bis (trimethylstannylvinyl) cuprate reagent 6 is described. Its addition to α,β-unsaturated ketones has been compared with other mixed cuprates.
