185-70-6Relevant articles and documents
Revisiting the Corey-Chaykovsky reaction: The solvent effect and the formation of β-hydroxy methylthioethers
Peng, Yu,Yang, Jin-Hui,Li, Wei-Dong Z.
, p. 1209 - 1215 (2007/10/03)
The classical Corey-Chaykovsky (CC) reaction of ketones in ethereal solvents (i.e., THF or Et2O) resulted in the production of a significant amount of β-hydroxy methylthioether 2 along with normal epoxide product 1. Some interesting and synthet
Reaction of Lithium with Alkylidene Halides and Carbonyl Compounds
Pasha, M. A.,Ravindranath, B.
, p. 781 - 782 (2007/10/02)
While benzylidene bromide reacts with aromatic aldehydes and lithium to give stilbenes, the reaction with aliphatic carbonyl compounds as well as that of alkylidene halides with carbonyl compounds and lithium are complicated by several competing side reactions.
Preparative Oxidation of Cycloalkanes with O(3P) Atoms. Microwave Discharge of CO2 as a Source of O(3P) Atoms.
Zadok, Elazar,Mazur, Yehuda
, p. 2223 - 2225 (2007/10/02)
Reaction of O atoms produced by CO2 discharge with cycloalkanes leads to their hydroxy, keto, and epoxy derivatives.The main products of oxidation of isomeric 1,2-dimethylcyclohexanes and cis-decalin were their respective tertiary alcohols formed with a high retention of configuration.This oxidation proceeds via radical mechanism, and the alcohols are formed by radical combination in a solvent cage.The influence of temperature and of O2 on the relative product distribution was investigated.