18547-28-9Relevant articles and documents
New syntheses with magnesium hydride part 2: Pathways to new complex hydrides and aluminium hydride
Knott, Wilfried
, p. 629 - 634 (2007/10/03)
The reaction between autocatalytically prepared magnesium hydride (Tego Magnan) and aluminium halides in ethers generates a new class of reducing agents, i.e. magnesium aluminium hydridohalides. By choosing dioxane-1,4 as solvent a route to an aluminium hydride dioxane complex is opened. The new reducing agents show outstanding selectivity especially in the field of organosilicones, combined with a maximum of safety in their application.