185906-70-1

Basic information

• Product Name: [Pt(CH₂CHCONHC(CH₃)2CH₂COCH₃)(P(C₆H₅)3)2]
• CAS NO: 185906-70-1
• Molecular Weight: 888.885
• Mol File: 185906-70-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pt(CH₂CHCONHC(CH₃)2CH₂COCH₃)(P(C₆H₅)3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pt(CH₂CHCONHC(CH₃)2CH₂COCH₃)(P(C₆H₅)3)2](185906-70-1)
• EPA Substance Registry System: [Pt(CH₂CHCONHC(CH₃)2CH₂COCH₃)(P(C₆H₅)3)2](185906-70-1)

Safety Data

• Hazardous Substances Data: 185906-70-1(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 2873-97-4 N-(1,1-dimethyl-3-oxobutyl)acrylamide 

Downstream Products

• 185906-81-4 [Pt(CH₂CHCONHC(CH₃)2CH₂COCH₃)(P(C₆H₅)3)(P(C₆H₁₁)3)] 

Relevant articles and documents

Synthesis and characterization of platinum(0) alkene complexes; X-ray crystal structure determinations on [Pt(trans-PhCH=CHCHO)(PPh3)2] and [Pt(trans-PhCH=CHCOMe)(PPh3)2]

Reaction of [Pt(C2H4)(PPh3)2] with a range of alkenes gave the complexes [Pt(alkene)(PPh3)2]. Complexes of alkenes bearing electron-withdrawing ligands were, predictably, more stable than those of electron-rich alkenes. The complexes were characterized by multinuclear (1H, 13C, 31P and 195Pt) NMR spectroscopy and the structures of the derivatives of trans-PhCH=CHCHO and trans-PhCH=CHCOMe were established by X-ray diffraction studies. The complexes reacted with PCy3 to give [Pt(alkene)(PCy3)(PPh3)], usually as a mixture of regioisomers. Copyright