186895-24-9Relevant articles and documents
Enantioselective total synthesis of ligraminol d and ligraminol e
Kumbhar, D. D.,Mane, Baliram B.,Waghmode, Suresh B.
, p. 2285 - 2289 (2019)
As a part of our ongoing research on the synthesis of bioactive constituents or molecules by using an organocatalytic approach, enantioselective total syntheses of ligraminol D and ligraminol E were achieved starting from a commercially available nonchiral aldehyde. Key steps in this synthesis were an asymmetric α-aminoxylation of an aldehyde and a Mitsunobu reaction.
First total synthesis and reassignment of absolute configuration of diosniponol A and B
Yadav,Singh, Vinay K.,Thirupathaiah,Reddy, A. Bal
, p. 4427 - 4429 (2014/08/05)
Enantioselective first total synthesis of diosniponol A and B has been achieved starting from commercially available vanillin. Wittig reaction, Keck allylation, and Prins cyclization reactions are the key steps involved in the target synthesis.
An organo-iron mediated chiral synthesis of (+)-(S)-[6]-Gingerol
Le Gall,Lellouche,Beaucourt
, p. 6521 - 6524 (2007/10/02)
A short and efficient synthesis of (+)-(S)-[6]-Gingerol is described. The key step is a highly stereoselective cycloaddition of a nitrile oxide with a chiral iron complexed triene.
