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1871-76-7

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1871-76-7 Usage

Chemical Properties

SLIGHTLY YELLOWISH CRYSTALLINE POWDER

Uses

Different sources of media describe the Uses of 1871-76-7 differently. You can refer to the following data:
1. Diphenylacetyl Chloride is a reagent used in the synthesis of β-lactam estrogen receptor antagonists promoting antiproliferative and anti-tubulin polymerizatiion activity.
2. Diphenylacetyl chloride was used as a reagent in regioselective acylation of cyclomalto-oligosaccharides. It was also used in the preparation of N-substituted amides having local anesthetic properties.

Check Digit Verification of cas no

The CAS Registry Mumber 1871-76-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,7 and 1 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1871-76:
(6*1)+(5*8)+(4*7)+(3*1)+(2*7)+(1*6)=97
97 % 10 = 7
So 1871-76-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H11ClO/c15-14(16)13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H

1871-76-7 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Price
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  • Alfa Aesar

  • (L00171)  Diphenylacetyl chloride, 90+%   

  • 1871-76-7

  • 10g

  • 448.0CNY

  • Detail
  • Alfa Aesar

  • (L00171)  Diphenylacetyl chloride, 90+%   

  • 1871-76-7

  • 50g

  • 1683.0CNY

  • Detail
  • Aldrich

  • (331589)  Diphenylacetylchloride  90%, technical grade

  • 1871-76-7

  • 331589-5G

  • 450.45CNY

  • Detail
  • Aldrich

  • (331589)  Diphenylacetylchloride  90%, technical grade

  • 1871-76-7

  • 331589-25G

  • 1,546.74CNY

  • Detail

1871-76-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2-diphenylacetyl chloride

1.2 Other means of identification

Product number -
Other names diphenylacetyl chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1871-76-7 SDS

1871-76-7Relevant articles and documents

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Pierce,Haden,Gano

, p. 408 (1945)

-

Ruthenium-catalysed one-pot regio- and diastereoselective synthesis of pyrrolo[1,2-a] indoles via cascade C-H functionalization/annulation

Singh, Sukhdev,Butani, Himanshu H.,Vachhani, Dipak D.,Shah, Anamik,Van Der Eycken, Erik V.

, p. 10812 - 10815 (2017)

A cascade approach has been developed towards dual C-C bond formation via consecutive C-H functionalization/cyclization giving access to pyrrolo[1,2-a]indoles in a highly regio- and diastereoselective manner using catalytic [Ru(p-cymene)Cl2]2. The methodology was further expanded to attain pentacyclic structures involving manifold C-C bond creation.

Triphenylacetic acid amides: Molecular propellers with induced chirality

Prusinowska, Natalia,Bendziska-Berus, Wioletta,Jelecki, Maciej,Rychlewska, Urszula,Kwit, Marcin

, p. 738 - 749 (2015)

The combination of electronic circular dichroism spectroscopy (ECD), X-ray diffraction, and theoretical calculations permitted a detailed description of an unexpected chirality transfer in triphenylacetamides, which is achieved solely through weak intramolecular interactions. The observed phenomenon proceeds as a cascade process. The triphenylacetamide chromophore is sensitive to even small changes in the relative size of the substituent attached to the stereogenic center. Substitution at the stereogenic center influences helicity of the distal trityl chromophore but does not affect its propeller shape. Deformation of the propeller shape and consequent loss of its C3 symmetry results mainly from substitution of the amide hydrogen and is connected with an increase in steric hindrance. As an outcome of our studies, a model of optical activity of chiral triphenylacetamides is proposed. The performed X-ray studies revealed that this novel class of chiral compounds is likely to be of additional value due to the porosity of the crystals.

Design and synthesis of novel N-[3-(benzimidazol-2-ylamino)phenyl]amine and N-[3-(benzoxazol-2-ylamino)phenyl]amine derivatives as potential anticancer agents

Kumar, Honnavalli Yogish,Murumkar, Prashant R.,Pawar, Vijay,Srinivasan, B. P.,Yadav, M. R.

, (2021/10/20)

In this contribution, we report the design, synthesis and cytotoxicity studies of a series of N-[3-(benzimidazol-2-yl-amino)phenyl]amine and N-[3-(benzoxazol-2-ylamino)phenyl]amine derivatives. In vitro cytotoxicity assay of 26 selected compounds was carried out at National Cancer Institute (NCI), USA. Out of them, compounds 10e (NSC D-762842/1) and 11s (NSC D-764942/1) have shown remarkable cytotoxicity with GI50 values ranging between “0.589–14.3?μM” and “0.276–12.3?μM,” respectively, in the representative nine subpanels of human tumor cell lines. Further, flow cytometry analysis demonstrated that compound 10e exerted cell cycle arrest at G2/M phase and showed dose-dependent enhancement in apoptosis in K-562 leukemia cancer cells.

Visible-Light-Assisted Gold-Catalyzed Fluoroarylation of Allenoates

Feng, Chao,Tang, Hai-Jun,Zhang, Xinggui,Zhang, Yu-Feng

supporting information, p. 5242 - 5247 (2020/02/28)

A strategically novel synthetic method for the fluoroarylation of allenic ester was developed that enables the expedient construction of a host of β-fluoroalkyl-containing cinnamate derivatives. The reaction proceeds through visible-light-promoted gold redox catalysis, occurs smoothly under very mild reaction conditions, accommodates a large variety of functional groups, and more importantly allows the incorporation of fluorine and aryl groups with excellent regio- and stereoselectivity. The concomitant activation mode for both the allene motif and the hydrogen fluoride is key for the success of the reaction.

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