19064-77-8

Basic information

• Product Name: N-(4-methylphenyl)-N-[(1Z)-phenylmethylidene]amine oxide
• CAS NO: 19064-77-8
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.2591
• Mol File: 19064-77-8.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 363.9°C at 760 mmHg
• Flash Point: 169.2°C
• Density: 1.117g/cm³
• Vapor Pressure: 3.66E-05mmHg at 25°C
• Refractive Index: 1.641
• CAS DataBase Reference: N-(4-methylphenyl)-N-[(1Z)-phenylmethylidene]amine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methylphenyl)-N-[(1Z)-phenylmethylidene]amine oxide(19064-77-8)
• EPA Substance Registry System: N-(4-methylphenyl)-N-[(1Z)-phenylmethylidene]amine oxide(19064-77-8)

Safety Data

• Hazardous Substances Data: 19064-77-8(Hazardous Substances Data)

Upstream product

• 99-99-0 1-methyl-4-nitrobenzene 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 99-77-4 ethyl 4-nitrobenzoate 
• 5405-15-2 N-benzyl-N-(4-methylphenyl)amine 
• 1137-96-8 N-(benzylidene)aniline N-oxide 

Downstream Products

• 35216-23-0 3t,5-diphenyl-2-p-tolyl-(3ar,6ac)-tetrahydro-pyrrolo[3,4-d]isoxazole-4,6-dione 
• 35216-23-0 3c,5-diphenyl-2-p-tolyl-(3ar,6ac)-tetrahydro-pyrrolo[3,4-d]isoxazole-4,6-dione 
• 35216-25-2 5-(4-methoxy-phenyl)-3t-phenyl-2-p-tolyl-(3ar,6ac)-tetrahydro-pyrrolo[3,4-d]isoxazole-4,6-dione 
• 35216-25-2 5-(4-methoxy-phenyl)-3c-phenyl-2-p-tolyl-(3ar,6ac)-tetrahydro-pyrrolo[3,4-d]isoxazole-4,6-dione 
• 52165-42-1 1,1-dimethyl-4-phenyl-3-p-tolyl-3,4-dihydro-[1,2,4,5]oxatriazino[4,5-b]phthalazine-6,11-dione 
• 52165-39-6 4'-phenyl-3'-p-tolyl-3',4'-dihydro-spiro[cyclohexane-1,1'-[1,2,4,5]oxatriazino[4,5-b]phthalazine]-6',11'-dione 
• 52165-44-3 4-phenyl-1,1-dipropyl-3-p-tolyl-3,4-dihydro-[1,2,4,5]oxatriazino[4,5-b]phthalazine-6,11-dione 
• 623-11-0 1-methyl-4-nitrosobenzene 
• 10066-20-3 1-hydroxy-2-phenylbenzimidazole N³-oxide 
• 31429-28-4 phenyl-p-tolylimino-acetonitrile 
• 14016-00-3 6-methyl-2-phenylbenzoxazole 
• 10205-58-0 6-methyl-2-phenyl-1,3-benzothiazole 
• 92533-30-7 N-Benzyl-N-(4-methylphenyl)hydroxylamine 

Relevant articles and documents

Nitrone synthesis via pair electrochemical coupling of Nitro-Compounds with Benzyl Alcohol Derivatives

Here we report a paired electrochemical coupling of readily accessible nitro-compounds with benzyl alcohols to yield nitrone derivatives. In this work, electrochemical behavior of nitrobenzene and benzyl alcohol derivatives was studied by cyclic voltammetry and controlled potential coulommetry. Electrochemical reactions have been performed in aqueous/ethanol (or acetonitrile) solutions by employing common graphite electrodes and a simple controlled current protocol which can make this strategy more appealing than other conventional pathways.

Polyfunctionalized biaryls accessed by a one-pot nucleophilic aromatic substitution and sigmatropic rearrangement reaction cascade under mild conditions

A practical synthetic method has been developed for polyfunctionalized biaryls based on a facile one-pot nucleophilic aromatic substitution (SNAr) reaction and [5,5]- or [3,3]-sigmatropic rearrangement reaction cascade. Under mild basic conditions, N-arylhydroxylamines reacted with o-activated fluoro (het)arenes to form N,O-diarylhydroxylamine intermediates which underwent spontaneously selective [5,5]-sigmatropic rearrangement reaction to produce diverse functionalized 4-amino-4′-hydroxy-1,1′-biaryls. A sequential SNAr reaction and [3,3]-sigmatropic rearrangement took place between N-arylhydroxylamines and 2-fluoropyridine derivatives or 4-fluorobenzonitrile to afford functionalized 2-amino-2′-hydroxy-1,1′-biaryls. As invaluable and unique building blocks, the resulting biaryls were applied in the straightforward synthesis of N2,O2-coronarene, carbazole, aza- and diaza carbazole derivatives.

Tandem Chiral Cu(II) Phosphate-Catalyzed Deoxygenation of Nitrones/Enantioselective Povarov Reaction with Enecarbamates

A new catalytic enantioselective tandem deoxygenation/aza-Diels-Alder reaction of nitrones with enecarbamates was serendipitously discovered in the presence of chiral copper(II) diphosphate complexes. This process affords a wide range of 4-aminotetrahydroquinolines in respectable yields under mild conditions with good to excellent ee values.