19073-15-5

Basic information

• Product Name: 1,3-Dioxolane, 2-methyl-2-(4-nitrophenyl)-
• Synonyms: 1,3-Dioxolane,2-methyl-2-(4-nitrophenyl);2-(4-nitrophenyl)-2-methyl-1,3-dioxolane;2-methyl-2-(4-nitro-phenyl)-[1,3]-dioxolane
• CAS NO: 19073-15-5
• Molecular Formula: C10H11NO4
• Molecular Weight: 209.202
• Mol File: 19073-15-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2-methyl-2-(4-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-methyl-2-(4-nitrophenyl)-(19073-15-5)
• EPA Substance Registry System: 1,3-Dioxolane, 2-methyl-2-(4-nitrophenyl)-(19073-15-5)

Safety Data

• Hazardous Substances Data: 19073-15-5(Hazardous Substances Data)

Upstream product

• 131496-48-5 2-methyl-2-(4-nitrophenyl)-1,3-oxathiolane 
• 107-21-1 ethylene glycol 
• 764-48-7 ethyleneglycol vinyl ether 
• 586-78-7 para-nitrophenyl bromide 
• 98-86-2 acetophenone 
• 6531-13-1 1-[4-nitrophenyl]-1-ethanol 
• 3674-77-9 2-methyl-2-phenyl-1,3-dioxolane 
• 100-19-6 (4-nitrophenyl)ethanone 

Downstream Products

• 37103-99-4 5-(2-methyl-1,3-dioxolan-2-yl)-3-phenyl-2,1-benzisoxazole 
• 3674-77-9 2-methyl-2-phenyl-1,3-dioxolane 
• 6135-51-9 2-([1,1'-biphenyl]-4-yl)-2-methyl-1,3-dioxolane 
• 92-91-1 biphenyl-4-acetaldehyde 
• 19073-16-6 4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine 
• 478692-36-3 3-(3-bromophenyl)-5-(2-methyl-[1,3]dioxolan-2-yl)benzo[c]isoxazole 
• 478692-39-6 3-(4-bromo-phenyl)-5-(2-methyl-[1,3]-dioxolan-2-yl)-benzo[c]isoxazole 
• 100-19-6 (4-nitrophenyl)ethanone 
• 935-46-6 7-methyl-1,4-dioxa-spiro[4.5]decane 
• 108-94-1 cyclohexanone 
• 4362-18-9 2-benzyl-2-methyl-1,3-dioxolane 

Relevant articles and documents

Catalytic application of sulfamic acid-functionalized magnetic Fe3O4nanoparticles (SA-MNPs) for protection of aromatic carbonyl compounds and alcohols: Experimental and theoretical studies

Protection techniques of functional groups within the structure of organic compounds are important synthetic methods against unwanted attacks from various reagents during synthetic sequences. Acetal and thioacetal groups are well known as protective funct

House bulb light-induced photochemical acetalization of carbonyl compounds catalyzed by Eosin Y

We have systematically studied the reactions of acetalization and found that high reaction efficiency can be achieved using cheap and readily available organic Eosin Y as catalyst. The reaction proceeds smoothly under house bulbs and shows excellent functional group tolerance. The substrates of the reaction system are compatible with aromatic aldehydes, aliphatic aldehydes, aromatic ketones, and cyclic ketones with high yields.

Direct synthesis of protected arylacetaldehydes by tetrakis(phosphane)- palladium-catalyzed arylation of ethyleneglycol vinyl ether

A range of aryl bromides undergo Heck reaction with ethylene glycol vinyl ether, in the presence of [PdCl(C3H5)]2/ cis,cis,cis-1,2,3,4-tetrakis[(diphenylphosphanyl)methyl]cyclopentane as catalyst, to give regioselectively protected arylacetaldehydes in good yields. The β-arylation products were obtained in with 93-100 % selectivity with electron-poor aryl bromides or heteroaryl bromides. Furthermore, this catalyst can be used at low loading, even for reactions with sterically hindered aryl bromides. The aryl vinyl ether intermediates undergo subsequent ketalisation to give the corresponding 2-benzyl-1,3-dioxolane derivatives. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.