19263-14-0Relevant articles and documents
Decatungstate as photoredox catalyst: Benzylation of electron-poor olefins
Montanaro, Sara,Ravelli, Davide,Merli, Daniele,Fagnoni, Maurizio,Albini, Angelo
supporting information; experimental part, p. 4218 - 4221 (2012/09/22)
Excited tetrabutylammonium decatungstate (TBADT), known to activate a variety of compounds via hydrogen atom transfer (HAT), has now been applied as a photoredox catalyst for the effective oxidative cleavage of benzyl silanes and radical benzylation of reducible olefins occurring in isolated yields from poor to excellent.
"ONE-POT" SYNTHESIS OF DISYMMETRICALLY α,α'-DISUBSTITUTED SUCCINIC ANHYDRIDES PRECURSORS
Dana, A.,Campagnole, M.,Bourgeois, M.J.,Montaudon, E.
, p. 2981 - 2988 (2007/10/03)
A "one-pot" synthesis for disymmetrically α,α'-disubstituted succinic anhydrides precursors isreported in the present paper.Substituents are aryl, primary or secondary alkyl groups.This reaction represents a simple and quick method with fair yields.
Samarium(II) iodide - HMPA: A very efficient system for the selective reduction of α,β,-unsaturated carbonyl compounds
Cabrera,Alper
, p. 5007 - 5008 (2007/10/02)
α,β,-unsaturated esters, acids, and an anhydride undergo efficient double bond reduction by SmI2/HMPA in tetrahydrofuran.
