192887-48-2

Basic information

• Product Name: Manganese, chloro(4-methylphenyl)-
• CAS NO: 192887-48-2
• Molecular Formula: C7H7ClMn
• Molecular Weight: 181.524
• Mol File: 192887-48-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Manganese, chloro(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Manganese, chloro(4-methylphenyl)-(192887-48-2)
• EPA Substance Registry System: Manganese, chloro(4-methylphenyl)-(192887-48-2)

Safety Data

• Hazardous Substances Data: 192887-48-2(Hazardous Substances Data)

Upstream product

• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 50670-50-3 p-(p-tolyl)benzonitrile 
• 133909-96-3 4'-methyl-[1,1'-biphenyl]-3-carbonitrile 
• 53040-92-9 4-(4-tolyl)anisole 
• 644-08-6 4-Methylbiphenyl 
• 59115-49-0 2-(p-tolyl)naphthalene 
• 24667-94-5 2-(4-methylphenyl)quinoline 
• 77232-13-4 2-p-tolyl-pyrimidine 
• 4423-10-3 4-(p-tolyl)pyridine 
• 4423-09-0 4-(3-pyridyl)toluene 
• 4467-06-5 2-(4-methylphenyl)pyridine 
• 127462-39-9 (Z)-1-methyl-4-(4-methylpent-1-en-1-yl)benzene 

Relevant articles and documents

TRANSITION METAL ?-COMPLEXES IN ORGANIC SYNTHESIS 5. CROSS-COUPLING OF ORGANOMANGANESE COMPOUNDS WITH ALKENYL IODIDES

Aryl organomanganese compounds ArMnX and Ph3MnLi (Ar = Ph, p-MeC6H4, p-MeOC6H4, p-ClC6H4, p-BrC6H4, α-naphthyl; X = Cl, Br) react with alkenyl iodides RR1C=CR2I (R = H, Pr, Bu, i-Bu, C6H13, CH2=CHCH2, Ph; R1 = H, Pr, C5H11; R2 = H, Pr, SiMe3) in THF at 0-20 deg C to give cross-coupling products RR1C=CR2Ar in high yields.