19364-92-2Relevant articles and documents
Reactions of N-(Pentafluorophenyl)carbonimidoyl dichloride with fluorinated benzenes in the presence of AlCl3
Petrova, Tamara D.,Platonov, Vyacheslav E.,Pokrovskii, Leonid M.,Rybalova, Tatyana V.,Gatilov, Yurii V.
, p. 1449 - 1466 (2002)
N-(Pentafluorophenyl)carbonimidoyl dichloride (1) reacts, in the presence of excess AlCl3, with fluorinated benzenes containing 1-5 fluorine atoms in the molecule. With fluoro- and 1,3,5-trifluorobenzene the reaction gives the corresponding imi
ATTOGRAM-LEVEL DETECTION AND RELATIVE RESPONSE OF STRONG ELECTROPHORES BY GAS CHROMATOGRAPHY WITH ELECTRON CAPTURE DETECTION.
Corkill,Joppich,Kuttab,Giese
, p. 481 - 485 (2007/10/02)
The responses as peak areas of some divergent compounds, most of which are strong electron absorbers, are measured by gas chromatography with electron capture detection (GC-ECD). The most sensitive compounds are derivatized lodothyronines, which are essentially 20-fold more sensitive than lindane. N,N-Dipentafluorobenzoylpentafluoroaniline, a somewhat less sensitive but more volatile substance, was selected for determination of a detection limit. The value was 90 ag(1. 6 multiplied by 10** minus **1**9 mol), largely due to an anomalous increase in its response at the trace level. This increases the reported sensitivity of GC-ECD by 100-fold.
