199847-74-0Relevant articles and documents
Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur
Bonini, Bianca Flavia,Franchini, Mauro Comes,Fochi, Mariafrancesca,Mazzanti, Germana,Ricci, Alfredo
, p. 3211 - 3217 (2007/10/03)
A detailed investigation of the desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.