199847-85-3

Basic information

• Product Name: (Z)-1-[dimethyl(phenyl)silyl]-3-methylbut-1-enethiol
• Synonyms: (Z)-1-[dimethyl(phenyl)silyl]-3-methylbut-1-enethiol
• CAS NO: 199847-85-3
• Molecular Weight: 236.453
• Mol File: 199847-85-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-[dimethyl(phenyl)silyl]-3-methylbut-1-enethiol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-[dimethyl(phenyl)silyl]-3-methylbut-1-enethiol(199847-85-3)
• EPA Substance Registry System: (Z)-1-[dimethyl(phenyl)silyl]-3-methylbut-1-enethiol(199847-85-3)

Safety Data

• Hazardous Substances Data: 199847-85-3(Hazardous Substances Data)

Upstream product

• 108-12-3 isopentanoyl chloride 
• 75583-57-2 lithium bis(dimethyl(phenyl)silyl)cuprate 
• 199847-86-4 1-(dimethylphenylsilyl)-3-methylbutan-1-one 

Downstream Products

• 199847-75-1 3-[(Z)-1-(Dimethyl-phenyl-silanyl)-3-methyl-but-1-enylsulfanyl]-propionic acid methyl ester 

Relevant articles and documents

Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur

A detailed investigation of the desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.