205491-15-2

Basic information

• Product Name: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester
• Synonyms: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester
• CAS NO: 205491-15-2
• Molecular Weight: 483.723
• Mol File: 205491-15-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester(205491-15-2)
• EPA Substance Registry System: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester(205491-15-2)

Safety Data

• Hazardous Substances Data: 205491-15-2(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 147959-18-0 (4S)-2,2-dimethyl-4-(2-hydroxyethyl)oxazolidine-3-carboxylic acid tert-butyl ester 
• 205491-14-1 methyl [(4S)-3-(tert-butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidin-4-yl]ethanoate 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 205491-17-4 Toluene-4-sulfonic acid (S)-2-tert-butoxycarbonylamino-4-(tert-butyl-diphenyl-silanyloxy)-butyl ester 
• 205491-18-5 Allyl-{(R)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-decyl}-carbamic acid tert-butyl ester 
• 205491-09-4 {(R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-decyl}-carbamic acid tert-butyl ester 
• 205491-23-2 (2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(hydroxy-phenyl-methyl)-5-nonyl-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 175550-96-6 (-)-(2S,3S,5R)-2-benzyl-3-(tert-butyldimethylsilyloxy)-5-nonylpyrrolidine-1-carboxylic acid tert-butyl ester 
• 158527-21-0 tert-butyl (2S,3S,5R)-2-benzyl-3-hydroxy-5-nonylpyrrolidine-1-carboxylate 
• 125356-66-3 (+)-preussin 
• 205491-16-3 (S)-tert-butyl (4-((tert-butyldiphenylsilyl)oxy)-1-hydroxybutan-2-yl)carbamate 

Relevant articles and documents

Novel route to the synthesis of hydroxylated pyrrolidine derivatives via the intramolecular reaction of γ-aminoallylstannane with aldehyde. Total synthesis of (+)-preussin

The thermal cyclization of γ-aminoallylstannane (8) having an aldehyde group gave β-hydroxypyrrolidine derivative (9a) as a sole product. This methodology was applied successfully to the total synthesis of (+)-preussin.