20908-27-4

Basic information

• Product Name: 2-Butenoic acid, 4-oxo-4-phenyl-, ethyl ester, (Z)-
• Synonyms: 4-oxo-4-phenyl-cis-crotonic acid ethyl ester;(Z)-ethyl-4-oxo-4-phenyl-2-butenoate;(Z)-4-Oxo-4-phenyl-but-2-enoic acid ethyl ester;4-Oxo-4-phenyl-cis-crotonsaeure-aethylester;ethyl 3-benzoylacrylate
• CAS NO: 20908-27-4
• Molecular Formula: C12H12O3
• Molecular Weight: 204.225
• Mol File: 20908-27-4.mol
• Article Data: 21

Chemical Properties

• Melting Point: 54 °C
• CAS DataBase Reference: 2-Butenoic acid, 4-oxo-4-phenyl-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 4-oxo-4-phenyl-, ethyl ester, (Z)-(20908-27-4)
• EPA Substance Registry System: 2-Butenoic acid, 4-oxo-4-phenyl-, ethyl ester, (Z)-(20908-27-4)

Safety Data

• Hazardous Substances Data: 20908-27-4(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 79865-14-8 α,β-dibromoethyl ester of β-acetylacrylic acid 
• 79865-17-1 2-butylthioethyl β-benzoylacrylate 
• 582-24-1 1-phenyl-2-hydroxyethanone 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 70-11-1 α-bromoacetophenone 
• 623-73-4 diazoacetic acid ethyl ester 
• 20718-17-6 2-(dimethyl(oxo)-λ⁶-sulfaneylidene)-1-phenylethan-1-one 
• 98-88-4 benzoyl chloride 
• 3282-32-4 2-diazo-acetophenone 
• 72036-37-4 ethyl 4-hydroxy-4-phenylbut-2-ynoate 
• 1074-12-0 phenylglyoxal hydrate 
• 15121-89-8 ethyl (E)-4-oxo-4-phenyl-2-butenoate 

Downstream Products

• 95317-68-3 3-benzylamino-4-oxo-4-phenyl-butyric acid ethyl ester 
• 3448-48-4 phenacyl-succinic acid 
• 77596-91-9 α-(2-Furylcarbonyl)-γ-oxobenzolbutansaeure-ethylester 
• 29113-53-9 γ-Oxo-α-(2-thienylcarbonyl)benzolbutansaeure-ethylester 
• 128040-87-9 ethyl 2-isopropyl-4-oxo-4-phenylbutanoate 
• 132162-23-3 (E)-2-Isopropyl-4-oxo-4-phenyl-but-2-enoic acid ethyl ester 
• 128040-90-4 3-Benzoyl-4-methyl-pentanoic acid ethyl ester 
• 128040-86-8 3,3-Dimethyl-2-(2-oxo-2-phenyl-ethyl)-butyric acid ethyl ester 
• 128040-89-1 3-Benzoyl-4,4-dimethyl-pentanoic acid ethyl ester 
• 128040-97-1 (E)-2-tert-Butyl-4-oxo-4-phenyl-but-2-enoic acid ethyl ester 
• 132590-42-2 2-Benzoyl-1-(3,4-dimethyl-phenyl)-4-oxo-3,3a,4,11c-tetrahydro-5-oxa-cyclopenta[c]phenanthrene-3-carboxylic acid ethyl ester 
• 6270-17-3 ethyl 3-benzoylpropanoate 
• 94402-76-3 Ethyl trans-2,3-Epoxy-4-oxo-4-phenylbutanoate 
• 98184-96-4 C₁₂H₁₃⁽²⁾HO₃ 

Relevant articles and documents

PHOTOISOMERIZATION OF 3-BENZOYLACRYLATES ON A SILCA GEL SURFACE: EFFECT OF REACTION ENVIRONMENT ON SELECTIVITY

On irradiation on a dry silica gel surface, 2-(N,N-dialkylamino)ethyl 3-benzoylacrylates undergo selective E-Z isomerization.Competing processes, such as remote-hydrogen abstraction via a charge-transfer state, with the photoisomerization in solution are

Chiral Hydroxytetraphenylene-Catalyzed Asymmetric Conjugate Addition of Boronic Acids to Enones

(S)-2,15-Br2-DHTP-catalyzed asymmetric conjugate addition of boronic acids to β-trifluoromethyl α,β-unsaturated ketones and enones was studied. The reaction afforded the corresponding Michael addition products in moderate to high yields with excellent enantioselectivities (up to 99:1 er). This catalytic system features mild reaction conditions, high efficiency, and tolerance to heteroarylboronic acids.

A robust multifunctional ligand-controlled palladium-catalyzed carbonylation reaction in water

A novel, hydrophilic and recyclable methoxypolyethylene glycol (PEG)-modulated s-triazine-based multifunctional Schiff base/N,P-ligand L9 was prepared and used in Pd-catalyzed Heck-type carbonylative coupling reactions, affording diverse chalcone derivatives and 1,4-dicarbonyl esters in good yields.