21087-29-6

Basic information

• Product Name: Cinnamyl chloride
• Synonyms: trans-Cinnamylchloride;(3-Chloro-1-propenyl)benzene;3-Chloro-1-phenyl-1-propene;Cinnamyl chloride;[(E)-3-Chloroprop-1-enyl]benzene;(E)-3-Chloro-1-phenyl-1-propene;(E)-3-Phenylallyl chloride;[(E)-3-Chloro-1-propenyl]benzene
• CAS NO: 21087-29-6
• Molecular Formula: C₉H₉Cl
• Molecular Weight: 152.62
• EINECS: 220-246-4
• Mol File: 21087-29-6.mol
• Article Data: 49

Chemical Properties

• Melting Point: −19 °C(lit.)
• Boiling Point: 108 °C12 mm Hg(lit.)
• Flash Point: 175 °F
• Appearance: /
• Density: 1.096 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0614mmHg at 25°C
• Refractive Index: n20/D 1.584(lit.)
• Storage Temp.: 0-6°C
• Water Solubility: 200 mg/L (20 ºC)
• CAS DataBase Reference: Cinnamyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Cinnamyl chloride(21087-29-6)
• EPA Substance Registry System: Cinnamyl chloride(21087-29-6)

Safety Data

• Hazard Codes: T+,Xn
• Statements: 22-26-34-43-36/37/38
• Safety Statements: 26-28-36/37/39-45-37/39
• RIDADR: UN 1760 8/PG 2
• WGK Germany: 3
• RTECS: CZ0919905
• Hazardous Substances Data: 21087-29-6(Hazardous Substances Data)

Usage

Uses

(E)-Cinnamyl chloride synthesis of aryl and heterocyclic polyenes which exhibit antioxidant activity.

InChI:InChI=1/C9H9Cl/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8H2

Upstream product

• 1986-47-6 tranylcypromine hydrochloride 
• 64-19-7 acetic acid 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 1826-67-1 vinyl magnesium bromide 
• 100-52-7 benzaldehyde 
• 100-58-3 phenylmagnesium bromide 
• 107-02-8 acrolein 
• 768-03-6 Phenyl vinyl ketone 
• 100-42-5 styrene 
• 50-00-0 formaldehyd 
• 4192-77-2 ethyl cinnamate 
• 75-62-7 Bromotrichloromethane 
• 3536-96-7 vinylmagnesium chloride 
• 7217-71-2 1-phenyl-2-propenyl acetate 

Downstream Products

• 99858-64-7 2-trans-cinnamylamino-ethanol 
• 40596-06-3 4-ethyl-3-phenyl-1-hexen-4-ol 
• 55552-39-1 3-ethyl-6-phenyl-hex-5t-en-3-ol 
• 74473-12-4 C₁₈H₁₇Cl 
• 74473-11-3 C₁₈H₁₇Cl 
• 40395-23-1 3-phenyl-1-heptene 
• 10201-58-8 (E)-1-heptenylbenzene 
• 19752-23-9 cinnamyltrimethylsilane 
• 104047-01-0 (3RS,4RS)-(E)-3-phenylhept-1,5-dien-4-ol 
• 94052-75-2 (1-phenyl-2-propenylidene)adamantane 
• 94052-76-3 (3-phenyl-2-propenylidene)adamantane 
• 94052-65-0 2-(1-phenyl-2-propenyl)-2-adamantanol 
• 94052-66-1 2-(3-phenyl-2-propenyl)-2-adamantanol 
• 82194-04-5 (E)-6-Phenyl-5-hexen-2-one oxime 

Relevant articles and documents

Geranyl-chlorid, ein einfaches Herstellungsverfahren

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FeCl2-mediated Nucleophilic Chlorination of Iodoalkanes Accelerated by Phenanthroline Ligand

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Organocatalytic Synthesis of Oxazolines and Dihydrooxazines from Allyl-Amides: Bypassing the Inherent Regioselectivity of the Cyclization

A selective and efficient methodology for the construction of either oxazolines or dihydrooxazines from the corresponding allyl-amides is reported. Bypassing the inherent selectivity of the cyclization and depending on the substitution pattern of the substrate, a selective epoxidation-cyclization was developed leading to either the five-membered or the six-membered ring, upon simple and complementary reaction conditions. The cyclization products were obtained in good to excellent yields and high selectivities. (Figure presented.).