213180-54-2

Basic information

• Product Name: (E)-1-(3-methoxyphenyl)-3-methylamino-3-(methylthio)propenethione
• Synonyms: (E)-1-(3-methoxyphenyl)-3-methylamino-3-(methylthio)propenethione
• CAS NO: 213180-54-2
• Molecular Weight: 253.389
• Mol File: 213180-54-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-(3-methoxyphenyl)-3-methylamino-3-(methylthio)propenethione(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(3-methoxyphenyl)-3-methylamino-3-(methylthio)propenethione(213180-54-2)
• EPA Substance Registry System: (E)-1-(3-methoxyphenyl)-3-methylamino-3-(methylthio)propenethione(213180-54-2)

Safety Data

• Hazardous Substances Data: 213180-54-2(Hazardous Substances Data)

Upstream product

• 282111-20-0 2-methyl-5-(3-methoxyphenyl)isothiazole-3-thione 
• 42766-11-0 5-(3-methoxyphenyl)-3H-1,2-dithiole-3-thione 
• 42766-21-2 5-(3-methoxyphenyl)-1,2-dithiole-3-one 

Relevant articles and documents

Novel synthesis of cis-nickel(II) 3-alkylimino-3-alkyl(or aryl)thio-1-arylpropenethiolates and their application to the preparation of 5-aryl-3-(arylthio)isothiazoles

Treatment of (E)-3-alkylamino-3-alkylthio-1-(thioaroyl)propenes 2 with Ni(OAc)2·4H2O in EtOH at room temperature gave cis-Ni(II)-3-alkylimino-3-alkylthio-1-aryl- propenethiolates 3 in excellent yields. Heating a mixture of 3 and alkyl- or arylthiols in 1,2-dichloroethane gave new ketene S,N-acetals 4 having new alkyl- or arylthio groups depending on the thiols employed. For the first time, 5-aryl-3-(arylthio)isothiazoles were prepared from 2 with an arylthio group according to a known procedure.