21430-87-5

Basic information

• Product Name: trans-{PtCl₂(ethylamine)4}⁽²⁺⁾
• CAS NO: 21430-87-5
• Molecular Weight: 446.323
• Mol File: 21430-87-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-{PtCl₂(ethylamine)4}⁽²⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: trans-{PtCl₂(ethylamine)4}⁽²⁺⁾(21430-87-5)
• EPA Substance Registry System: trans-{PtCl₂(ethylamine)4}⁽²⁺⁾(21430-87-5)

Safety Data

• Hazardous Substances Data: 21430-87-5(Hazardous Substances Data)

Upstream product

• 21500-56-1 tetrachloro(ethylenediamine)platinum(IV) 
• 144754-55-2 platinum(IV)Cl₄(a-dmen) 
• 137736-91-5 platinum(IV)Cl₄(meen) 
• 23856-42-0 [Pt(propylenediamine)Cl₄] 

Relevant articles and documents

Atom-transfer and outer-sphere reductions of platinum(IV) complexes. A comparative kinetic investigation

Reductions of platinum(IV) complexes of the type (N-N=en, meen, dmen, tmen, 1,2-pn, 1,3-pn) by FeCp2, Bu4NI and (ClO4)2 in the presence of Et4NCl have been kinetically investigated in methanol solution.The reactions with FeCp2 or Bu4NI obey e second-order rate law reductant), whereas the rate law for the reactions with (ClO4)2 in the presence of Et4NCl is: rate = Pt(II)+kPt(II)->2+4>.The reactivity of the complexes is enhanced by an increased steric hindrance of the N-N ligand.Such a reactivity trend is likely to be related to a parallel increased thermodynamic tendency of platinum(IV) towards reduction.The effect of steric hindrance on the rate is less pronounced in the reaction with 2+ probably due to a direct interaction between the N-N and the NH2Et ligands in the activated complex