21699-64-9

Basic information

• Product Name: Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel-
• CAS NO: 21699-64-9
• Molecular Formula: C10H10O
• Molecular Weight: 146.189
• Mol File: 21699-64-9.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel-(21699-64-9)
• EPA Substance Registry System: Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel-(21699-64-9)

Safety Data

• Hazardous Substances Data: 21699-64-9(Hazardous Substances Data)

Upstream product

• 67965-28-0 (1-chloroprop-2-enyl)trimethyl silane 
• 100-52-7 benzaldehyde 
• 75-77-4 chloro-trimethyl-silane 
• 106-95-6 allyl bromide 
• 341525-05-1 2-Bromo-1-phenyl-but-3-en-1-ol 
• 88086-64-0 (1S,2R)-2-Chloro-1-phenyl-but-3-en-1-ol 
• 107-05-1 3-chloroprop-1-ene 
• 627-15-6 1,3-dibromopropene 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 5693-99-2 (±)-3-phenyloxirane-2-carbaldehyde 
• 124-41-4 sodium methylate 
• 74327-21-2 3-chloro-1-iodoprop-2(E/Z)-ene 
• 1072-43-1 propylene sulphide 
• 100-51-6 benzyl alcohol 

Downstream Products

• 123614-01-7 (Z)-1-phenyl-2,5-hexadien-1-ol 
• 114467-64-0 (E)-1-phenyl-2,5-hexadien-1-ol 
• 72486-03-4 (E)-1,4-diphenylbut-2-en-1-ol 
• 84363-90-6 1,2-diphenylbut-3-en-1-ol 
• 123614-00-6 (Z)-1,4-diphenylbut-2-en-1-ol 
• 123614-02-8 (Z,E)-1,6-diphenyl-2,5-hexadien-1-ol 
• 114467-65-1 (2E,5E)-1,6-diphenyl-2,5-hexadien-1-ol 

Relevant articles and documents

Novel reaction course of thiiranes to vinyloxiranes: Reaction of benzyne with thiiranes and aldehydes

Reaction of 2 molar amount of 2-(trimethylsilyl)phenyl triflate with thiiranes and aldehydes in the presence of CsF afforded vinyloxiranes in one-pot operation. Reaction of benzyne with thiiranes gave the corresponding alkenyl phenyl sulfides, which furth

A One-Pot Reaction toward the Diastereoselective Synthesis of Substituted Morpholines

The diastereoselective synthesis of various substituted morpholines has been achieved from vinyloxiranes and amino-alcohols under sequential Pd(0)-catalyzed Tsuji-Trost/Fe(III)-catalyzed heterocyclization. Using the same strategy, 2,6-, 2,5-, and 2,3-disubstituted as well as 2,5,6- and 2,3,5-trisubstituted morpholines were obtained in good to excellent yields and diastereoselectivities.

[2,3] Sigmatropic rearrangement of unstable sulfur ylides from allyl sulfonium salts. Comparative study of electrochemical reduction with the base method and mechanism elucidation by the MO method

The cathodic reduction of sulfonium salts in acetonirile under the presence and absence of benzaldehyde were carried out and compared with the results of the base method. Under the presence of benzaldehyde, the electrochemical reduction gave epoxides as a