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2212-10-4

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2212-10-4 Usage

Chemical Properties

Colorless transparent liquid

Check Digit Verification of cas no

The CAS Registry Mumber 2212-10-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,2,1 and 2 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2212-10:
(6*2)+(5*2)+(4*1)+(3*2)+(2*1)+(1*0)=34
34 % 10 = 4
So 2212-10-4 is a valid CAS Registry Number.
InChI:InChI=1/C6H15ClO2Si/c1-4-8-10(3,6-7)9-5-2/h4-6H2,1-3H3

2212-10-4 Well-known Company Product Price

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  • Aldrich

  • (597546)  (Chloromethyl)methyldiethoxysilane  97%

  • 2212-10-4

  • 597546-25G

  • 2,224.17CNY

  • Detail

2212-10-4Relevant articles and documents

Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry

Weisheim, Eugen,Reuter, Christian G.,Heinrichs, Peter,Vishnevskiy, Yury V.,Mix, Andreas,Neumann, Beate,Stammler, Hans-Georg,Mitzel, Norbert W.

, p. 12436 - 12448 (2015)

Directed tridentate Lewis acids based on the 1,3,5-trisilacyclohexane skeleton with three ethynyl groups [CH2Si(Me)(C2H)]3 were synthesised and functionalised by hydroboration with HB(C6F5)2, yielding the ethenylborane {CH2Si(Me)[C2H2B(C6F5)2]}3, and by metalation with gallium and indium organyls affording {CH2Si(Me)[C2M(R)2]}3 (M=Ga, In, R=Me, Et). In the synthesis of the backbone the influence of substituents (MeO, EtO and iPrO groups at Si) on the orientation of the methyl group was studied with the aim to increase the abundance of the all-cis isomer. New compounds were identified by elemental analyses, multi-nuclear NMR spectroscopy and in some cases by IR spectroscopy. Crystal structures were obtained for cis-trans-[CH2Si(Me)(Cl)]3, all-cis-[CH2Si(Me)(H)]3, all-cis-[CH2Si(Me)(C2H)]3, cis-trans-[CH2Si(Me)(C2H)]3 and all-cis-[CH2Si(Me)(C2SiMe3)]3. A gas-phase electron diffraction experiment for all-cis-[CH2Si(Me)(C2H)]3 provides information on the relative stabilities of the all-equatorial and all-axial form; the first is preferred in both solid and gas phase. The gallium-based Lewis acid {CH2Si(Me)[C2Ga(Et)2]}3 was reacted with a tridentate Lewis base (1,3,5-trimethyl-1,3,5-triazacyclohexane) in an NMR titration experiment. The generated host-guest complexes involved in the equilibria during this reaction were identified by DOSY NMR spectroscopy by comparing measured diffusion coefficients with those of the suitable reference compounds of same size and shape.

Effect of substituents on the silicon atom on etherification of organochlorosilanes with ethanol

Chernyshev,Belyakova,Komarov,Bykovchenko

, p. 1038 - 1040 (2007/10/03)

The kinetics of etherification of organochlorosilanes with various substituents on the silicon atom with ethanol were studied. The etherification rate is mostly controlled by the inductive constants of the substituents and increases as the electron-acceptor power of the substituents increases. The ρ* value in the Taft equation for etherification of organochlorosilanes with ethanol was determined.

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