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22144-60-1

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22144-60-1 Usage

Uses

(R)-(+)-1-Phenyl-1-butanol can be used as a substrate in the thermodynamic studies of:Transesterification of phenyl alkanols with butyl acetate in the presence of lipase enzyme.Reduction of phenyl alkanones in the presence of ketoreductase enzyme.

Check Digit Verification of cas no

The CAS Registry Mumber 22144-60-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,1,4 and 4 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 22144-60:
(7*2)+(6*2)+(5*1)+(4*4)+(3*4)+(2*6)+(1*0)=71
71 % 10 = 1
So 22144-60-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H14O/c1-2-6-10(11)9-7-4-3-5-8-9/h3-5,7-8,10-11H,2,6H2,1H3/t10-/m1/s1

22144-60-1 Well-known Company Product Price

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  • Aldrich

  • (317314)  (R)-(+)-1-Phenyl-1-butanol  97%

  • 22144-60-1

  • 317314-1G

  • 1,579.50CNY

  • Detail

22144-60-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (1R)-1-Phenyl-1-butanol

1.2 Other means of identification

Product number -
Other names (3R)-(+)-1-Benzyl-3-(tert-butoxycarbonylamino)pyrrolidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:22144-60-1 SDS

22144-60-1Relevant articles and documents

Cobalt-catalyzed asymmetric hydrogenation of ketones: A remarkable additive effect on enantioselectivity

Du, Tian,Wang, Biwen,Wang, Chao,Xiao, Jianliang,Tang, Weijun

supporting information, p. 1241 - 1244 (2020/10/02)

A chiral cobalt pincer complex, when combined with an achiral electron-rich mono-phosphine ligand, catalyzes efficient asymmetric hydrogenation of a wide range of aryl ketones, affording chiral alcohols with high yields and moderate to excellent enantioselectivities (29 examples, up to 93% ee). Notably, the achiral mono-phosphine ligand shows a remarkable effect on the enantioselectivity of the reaction.

Ruthenium-catalyzed hydrogenation of aromatic ketones using chiral diamine and monodentate achiral phosphine ligands

Wang, Mengna,Zhang, Ling,Sun, Hao,Chen, Qian,Jiang, Jian,Li, Linlin,Zhang, Lin,Li, Li,Li, Chun

, (2021/03/24)

The Ru-catalyzed asymmetric hydrogenation of ketones with chiral diamine and monodentate achiral phosphine has been developed. A wide range of ketones were hydrogenated to afford the corresponding chiral secondary alcohols in good to excellent enantioselectivities (up to 98.1% ee). In addition, an appropriate mechanism for the asymmetric hydrogenation was proposed and verified by NMR spectroscopy.

Method for asymmetric functionalization of nickel-hydrogen catalytic olefin migration promoted by ligand relay strategy

-

Paragraph 0089-0091, (2021/06/12)

The invention discloses a method for asymmetric functionalization of nickel-hydrogen catalytic olefin migration promoted by a ligand relay strategy. Under the action of a metal nickel salt, an achiral ligand, a chiral ligand, alkali, a hydrogen source, an additive and the like, olefin and various electrophilic reagents are dissolved in an organic solvent for reaction, and the chiral compound with excellent regioselectivity and enantioselectivity is obtained. According to the method, the chiral compound containing various functional groups can be efficiently synthesized, the product has high enantioselectivity, the raw materials are simple and easy to obtain, and operation is easy and convenient.

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