2386-64-3

Basic information

• Product Name: Ethylmagnesium chloride
• Synonyms: ETHYLMAGNESIUM CHLORIDE;Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/l);chloroethylmagnesium;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N DIETHYL ETHER;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION &;ETHYLMAGNESIUM CHLORIDE SOLUTION, ~2.8 M IN TETRAHYDROFURAN;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN;ETHYLMAGNESIUM CHLORIDE, 2M SOLUTION IN TETRAHYDROFURAN
• CAS NO: 2386-64-3
• Molecular Formula: C₂H₅ClMg
• Molecular Weight: 88.82
• EINECS: 219-206-9
• Product Categories: GRIGNARD REAGENTS;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;grignard reagent
• Mol File: 2386-64-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 66℃
• Flash Point: 1 °F
• Appearance: Yellow to dark brown/Solution
• Density: 1.00 g/mL at 20 °C
• Storage Temp.: water-free area
• Water Solubility: reacts
• Sensitive: Air & Moisture Sensitive
• BRN: 3647886
• CAS DataBase Reference: Ethylmagnesium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Ethylmagnesium chloride(2386-64-3)
• EPA Substance Registry System: Ethylmagnesium chloride(2386-64-3)

Safety Data

• Hazard Codes: F+,C,F
• Statements: 12-14-20/21/22-34-40-14/15-11-22-19-67-37
• Safety Statements: 26-30-36/37/39-43-45-7/8-33-16-6A-43A-24/25
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 1
• F: 1-3-10
• TSCA: Yes
• HazardClass: 4.3
• PackingGroup: II
• Hazardous Substances Data: 2386-64-3(Hazardous Substances Data)

Usage

Chemical Properties

DARK BROWN SOLUTION

Uses

Different sources of media describe the Uses of 2386-64-3 differently. You can refer to the following data:
1. Grignard-type reactions.
2. Ethylmagnesium chloride solution can be used: In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids. In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

Definition

CHEBI:Ethylmagnesium chloride is an alkylmagnesium halide. It has a role as a Grignard reagent.

Hazard

Flammable, dangerous fire risk.

InChI:InChI=1/C2H5.ClH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1/rC2H5Mg.ClH/c1-2-3;/h2H2,1H3;1H/q+1;/p-1

Upstream product

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Relevant articles and documents

HALIDE REDUCTION DIHYDROCARBYLMAGNESIUM MIXTURES

This invention provides a process for reducing the amount of soluble halide in a solution comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, and an initial amount of soluble halide. The process comprises mixing at least one alkali metal with the solution at a mole ratio of alkali metal to magnesium of less than about 1:2.5, thereby forming precipitated soluble halides. Also provided by this invention is a process for reducing the amount of soluble halide in a slurry comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, solids from the formation of said dihydrocarbylmagnesium compound, and an initial amount of soluble halide. This process comprises mixing at least one alkali metal with the slurry at a mole ratio of alkali metal to magnesium of less than about 1:1.25, thereby forming precipitated soluble halides.

Nodulisporic acid derivatives

The present invention relates to novel nodulosporic acid derivatives, which are acaricidal, antiparasitic, insecticidal and anthelmintic agents.