2395-96-2Relevant articles and documents
Barnett,Needham
, p. 4134 (1971)
Useful Routes to 9-Anthryl Ethers and Sulfides
Pirkle, William H.,Finn, John M.
, p. 2779 - 2780 (1983)
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Isolation of a hydrogen-bonded complex based on the anthranol/anthroxyl pair: Formation of a hydrogen-atom self-exchange system
Hirao, Yasukazu,Saito, Tohru,Kurata, Hiroyuki,Kubo, Takashi
, p. 2402 - 2405 (2015)
A hydrogen-bonded complex was successfully isolated as crystals from the anthranol/anthroxyl pair in the self-exchange proton-coupled electron transfer (PCET) reaction. The anthroxyl radical was stabilized by the introduction of a 9-anthryl group at the carbon atom at the 10-position. The hydrogen-bonded complex with anthranol self-assembled by π-π stacking to form a one-dimensional chain in the crystal. The conformation around the hydrogen bond was similar to that of the theoretically predicted PCET activated complex of the phenol/phenoxyl pair. X-ray crystal analyses revealed the self-exchange of a hydrogen atom via the hydrogen bond, indicating the activation of the self-exchange PCET reaction between anthranol and anthroxyl. Magnetic measurements revealed that magnetic ordering inside the one-dimensional chain caused the inactivation of the self-exchange reaction.
Magnetic substance and magnetic substance manufacturing method
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Page/Page column 17; 18, (2017/11/01)
[object] A magnetization technique that enhances magnetic properties of an organic compound is provided without damaging properties of the organic compound or while maintaining the structure of the organic compound. [solution] The present disclosure is a method for manufacturing a magnetic substance composed of crystals of a magnetization target compound and an electron acceptor by combining the magnetization target compound with the electron acceptor; forming a solution by dissolving a mixture of the magnetization target compound and the electron acceptor in a solvent; maintaining the solution in a very low temperature state and allowing the solution to deposit the crystals of the magnetic target compound and the electron acceptor; and separating the crystals from the solvent.