2422-86-8 Usage
Synthesis Reference(s)
Journal of the American Chemical Society, 97, p. 2299, 1975 DOI: 10.1021/ja00841a067The Journal of Organic Chemistry, 52, p. 4772, 1987 DOI: 10.1021/jo00230a022
Check Digit Verification of cas no
The CAS Registry Mumber 2422-86-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,2 and 2 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 2422-86:
(6*2)+(5*4)+(4*2)+(3*2)+(2*8)+(1*6)=68
68 % 10 = 8
So 2422-86-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H8/c1-2-6-4-5-7(6)3-1/h1-2,4-7H,3H2
2422-86-8Relevant articles and documents
Stereochemistry of the Bicyclopentane Ringopening; Thermolysis of Tricyclo2,4>heptane Derivatives
Roth, Wolfgang R.,Klaerner, Frank-Gerit,Grimme, Wolfram,Koeser, Hans G.,Busch, Ralf,et al.
, p. 2717 - 2737 (2007/10/02)
Thermolysis of the anti-tricyclic compounds 6, 22 and 34 proceeds preferentially by concerted 2s+?2a>-reactions and leads to cis,trans-olefines 8, 24 and 37.The rearrangement of the syn-isomers on the other hand seems to be a nonconcerted reaction yielding the diradicals 15, 27 and 36.
