24325-17-5

Basic information

• Product Name: Hexanedioic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, 1-(phenylmethyl) ester, (S)-
• CAS NO: 24325-17-5
• Molecular Formula: C21H23NO6
• Molecular Weight: 385.417
• Mol File: 24325-17-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Hexanedioic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, 1-(phenylmethyl) ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanedioic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, 1-(phenylmethyl) ester, (S)-(24325-17-5)
• EPA Substance Registry System: Hexanedioic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, 1-(phenylmethyl) ester, (S)-(24325-17-5)

Safety Data

• Hazardous Substances Data: 24325-17-5(Hazardous Substances Data)

Upstream product

• 65926-39-8 (R)-benzyl 2-(((benzyloxy)carbonyl)amino)-3-iodopropanoate 
• 79-10-7 acrylic acid 
• 24325-14-2 (2S)-2-[(phenylmethoxy)carbonyl]aminoadipic acid 
• 100-44-7 benzyl chloride 
• 501-53-1 benzyl chloroformate 
• 102922-72-5 (S)-2-(((benzyloxy)carbonyl)amino)-6-hydroxyhexanoic acid 
• 657-27-2 L-Lysine hydrochloride 
• 14511-39-8 2(S)-2-amino-6-(benzylideneamino)hexanoic acid 
• 2212-75-1 N₂-[(benzyloxy)carbonyl]-L-lysine 
• 24325-12-0 (+/-)-2-chloroacetaminohexanedioic acid 
• 81306-82-3 N-carbobenzoxy-L-α-aminoadipic acid bis-(p-nitrobenzyl) ester 
• 81306-83-4 δ-(p-nitrobenzyl) N-carbobenzoxy-L-α-aminoadipiate 
• 84246-48-0 C₂₇H₃₀N₄O₄ 
• 84246-50-4 (S)-2-Benzyloxycarbonylamino-6-formyloxy-hexanoic acid benzyl ester 

Downstream Products

• 157701-51-4 1-benzyl (2S,)-2-benzyloxycarbonylamino-5-[(N-methylsulphonyl)carbamoyl]-pentanoate 
• 81306-86-7 N-benzyloxycarbonyl-α-benzylester-δ-L-α-aminoadipoyl-O-benzyl-D-serinyl-D-valine benzylester 
• 69644-78-6 bis[Aad(-Cys-D-Val)] 
• 103548-47-6 (S)-benzyl 2-benzyloxycarbonylamino-9-(4-imidazolyl)-7-azanonanoate 
• 79761-07-2 N-benzyloxycarbonyl-α-benzyl-δ-(L-α-aminoadipoyl)-S-benzyl-L-<3-13C>cysteinyl-D-<3-13C>valine benzyl ester 
• 79761-05-0 N-benzyloxycarbonyl-α-benzyl-δ-(L-α-aminoadipoyl)-S-benzyl-L-cysteinyl-D-valine benzyl ester 
• 79761-15-2 N-benzyloxycarbonyl-α-benzyl-δ-(L-α-aminoadipoyl)-S-benzyl-L-<3-13C>cysteine 
• 79761-10-7 [(N-benzyloxycarbonyl)-(α-benzyl)-δ-(L-α-aminoadipoyl)]-S-benzyl-L-cysteine 
• 87829-75-2 (R)-6-[((S)-5-Benzyloxycarbonyl-5-benzyloxycarbonylamino-pentylamino)-methyl]-2-(4-nitro-phenyl)-[1,3]oxazinane-3-carboxylic acid benzyl ester 
• 87829-73-0 (S)-3,4-Dihydro-2H-pyridine-1,2-dicarboxylic acid dibenzyl ester 
• 87829-74-1 (S)-benzyl 6-oxo-2-benzyloxycarbonylaminohexanoate 
• 21566-74-5 (L-α-amino-δ-adipyl)-L-cysteinyl-D-valine 
• 159453-15-3 -S-phenyl-L-cysteine 
• 247904-25-2 (S)-2-[[4-[N-[[3,4-dihydro-2,7-dimethyl-4-oxo-3-[(pivaloyloxy)methyl]-6-quinazolinyl]methyl]-N-prop-2-ynylamino]-2-fluorobenzoyl]amino]-5-[N-(methanesulfonyl)amino]carboxypentanoic acid 

Relevant articles and documents

Applications of Radical Addition Reactions to the Synthesis of a C-Glucoside and a Functionalised Amino-acid

Addition of carbon radicals derived from tetra-acetylglucosyl and β-alanyl derivatives to acrylic acid or esters provides a short route to a C-glucoside and a functionalised α-amino-acid, respectively.

SYNTHESIS OF N-BENZYLOXYCARBONYL-L-α-AMINOADIPIC ACID, α-BENZYL ESTER

A new synthesis of N-benzyloxycarbonyl-L-α-aminoadipic acid, α-benzyl ester (1) from L-lysine monohydrochloride (2) is reported.

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The racemate end both the (R)- and (S)-forms of gizzerosine were synthesised, and the (S)-isomer was identified as the toxic substance in fish meal causing severe gizzard erosion (black vomit) in chicks.