24712-22-9Relevant articles and documents
Syntheses of diazadithiacrown ethers containing appended coumarin or 1-aminonaphthalene sidearms
Song, Hua-Can,Chen, Yi-Wen,Yao, Jun-Hua,Xu, Zun-Le,Bradshaw, Jerald S.,Savage, Paul B.,Izatt, Reed M.
, p. 475 - 479 (2003)
Six crown ethers containing two coumarin (11, 13, 14, 16, 17 and 19) or two 1-aminonaphthalene (15 and 20) fragments as sidearms and two crown ethers bearing one coumarin (12 and 18) arm were synthesized by a nucleophilic substitution of the secondary macrocyclic amine function on the alkyl halide. The major products of these reactions were the diazadithiacrown ethers containing two sidearms. In some cases, one-armed diazadithiacrown ethers were separated as minor products, although more than 2.5 mmoles of alkyl halide were used for 1.0 mmole of macrocyclic diamine.