24808-74-0

Basic information

• Product Name: (E)-(3-methoxybut-1-en-1-yl)benzene
• Synonyms: (E)-(3-methoxybut-1-en-1-yl)benzene
• CAS NO: 24808-74-0
• Molecular Weight: 162.232
• Mol File: 24808-74-0.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: (E)-(3-methoxybut-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3-methoxybut-1-en-1-yl)benzene(24808-74-0)
• EPA Substance Registry System: (E)-(3-methoxybut-1-en-1-yl)benzene(24808-74-0)

Safety Data

• Hazardous Substances Data: 24808-74-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 154503-15-8 ((E)-3-Isopropoxy-but-1-enyl)-benzene 
• 14371-10-9 (E)-3-phenylpropenal 
• 557-20-0 diethylzinc 
• 1896-62-4 (E)-benzalacetone 
• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 74-88-4 methyl iodide 
• 75-16-1 methylmagnesium bromide 
• 4364-06-1 (E)-cinnamaldehyde dimethylacetal 
• 81176-43-4 (S)-trans-4-phenyl-3-buten-2-ol 
• 17488-65-2 4-phenylbut-3-en-2-ol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 32644-22-7 1-methyl-3-phenylallene 
• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 

Downstream Products

• 101266-90-4 (E)-(3-propoxybut-1-enyl)benzene 
• 101266-90-4 ((E)-3-Propoxy-but-1-enyl)-benzene 
• 169694-34-2 (3-methyl-1,5-hexadien-1-yl)-benzene 
• 73222-65-8 1-methyl-3-phenylhexa-1,5-diene 
• 112528-98-0 (E)-(±)-2-methyl-4-phenylbut-3-enenitrile 
• 1896-62-4 (E)-benzalacetone 
• 7302-00-3 (E)-1,3-diphenyl-1-butene 
• 106728-00-1 (E)-1,3-diphenyl-1-oxo-4-hexene 
• 106728-01-2 (E)-1,5-diphenyl-3-methyl-1-oxo-4-pentene 
• 144789-20-8 (E)-1-phenyl-3(S)-(trimethylsilyl)-1-butene 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 233672-89-4 3-phenyl-1-methyl-prop-2-en-1-azide 
• 74608-23-4 4-methyl-N-(4-phenylbut-3-en-2-yl)benzenesulfonamide 
• 1309466-63-4 C₁₄H₂₁O₃PS 

Relevant articles and documents

Allylic Substitution Catalyzed by a New Molybdenum Complex

A new molybdenum(II) complex (E), generated in situ from Mo(CO)6 by sequential treatment with PhCH2(Et)3N+Cl- and CF3SO3Ag (3 equiv.), has been found to catalyze the substitution of allylic acetates with MeOH (4 -> 5 8; 9

Nickel-Mediated Enantiospecific Silylation via Benzylic C-OMe Bond Cleavage

Benzylic stereocenters are found in bioactive and drug molecules, as enantiopure benzylic alcohols have been used to build such a stereogenic center, but are limited to the construction of a C-C bond. Silylation of alkyl alcohols has the potential to build bioactive molecules and building blocks; however, the development of such a process is challenging and unknown. Herein, we describe an unprecedented AgF-assisted nickel catalysis in the enantiospecific silylation of benzylic ethers.

Oxidative cleavage of allyl ethers by an oxoammonium salt

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.