2525-40-8

Basic information

• Product Name: prop-2-ynylsulfonylbenzene
• Synonyms: prop-2-ynylsulfonylbenzene;PHENYL PROPARGYL SULFONE
• CAS NO: 2525-40-8
• Molecular Formula: C₉H₈O₂S
• Molecular Weight: 180.22
• Mol File: 2525-40-8.mol
• Article Data: 22

Chemical Properties

• Melting Point: 93 °C
• Boiling Point: 334.6°Cat760mmHg
• Flash Point: 194.8°C
• Appearance: /
• Density: 1.217g/cm³
• Vapor Pressure: 0.000246mmHg at 25°C
• Refractive Index: 1.551
• CAS DataBase Reference: prop-2-ynylsulfonylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-ynylsulfonylbenzene(2525-40-8)
• EPA Substance Registry System: prop-2-ynylsulfonylbenzene(2525-40-8)

Safety Data

• Hazardous Substances Data: 2525-40-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H8O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h1,3-7H,8H2

Upstream product

• 98-09-9 benzenesulfonyl chloride 
• 5651-88-7 phenyl propargyl sulfide 
• 873-55-2 sodium benzenesulfonate 
• 106-96-7 propargyl bromide 
• 108-98-5 thiophenol 
• 220961-10-4 ((2-bromo-2-propenyl)sulfonyl)benzene 
• 618-41-7 Benzenesulfinic acid 

Downstream Products

• 140934-66-3 (3aR,7aS)-3-Benzenesulfonyl-2,6,7a-trimethyl-3a,7a-dihydro-furo[3,2-b]pyridine 
• 140934-67-4 (2aS,4aS,7aR)-7-Benzenesulfonyl-1-[1-benzenesulfonyl-meth-(E)-ylidene]-3,4a,6-trimethyl-2,2a,4a,7a-tetrahydro-1H-5-oxa-7b-aza-cyclobuta[e]indene 
• 109787-38-4 (E)-<<2-<(E)-(2-butenyloxy)>-1-propenyl>sulfonyl>benzene 
• 109787-39-5 [2-(1-Methyl-allyloxy)-prop-2-ene-1-sulfonyl]-benzene 
• 109787-40-8 (E)-<<2-<(1-ethyl-2-propenyl)oxy>-1-propenyl>sulfonyl>benzene 
• 109787-36-2 E-<<2-(2-propenyloxy)-1-propenyl>sulfonyl>benzene 
• 2525-42-0 phenylsulfonylpropa-1,2-diene 
• 5000-44-2 1-phenylsulfonyl-2-propanone 
• 109787-36-2 Z-<<2-(2-propenyloxy)-1-propenyl>sulfonyl>benzene 
• 109787-35-1 <<2-(2-propenyloxy)-2-propenyl>sulfonyl>benzene 
• 109787-43-1 <<2-<(E)-(3-phenyl-2-propenyl)oxy>-2-propenyl>sulfonyl>benzene 
• 125914-23-0 3-(phenylsulfonyl)-2-(ethylthio)-1-propene 
• 202804-00-0 3-Benzenesulfonylmethyl-but-3-en-1-ol 
• 96965-01-4 3-(3,5-dichloro-2,4,6-trimethylphenyl)-5-<(phenylsulfonyl)methyl>isoxazole 

Relevant articles and documents

COMPOSITES, METHODS AND USES THEREOF

The present invention relates, in general terms, to methods of catalysing a reaction, including the steps of contacting a chemical entity comprising a sulphide moiety with a composite and an oxidant. The composite acts as a heterogeneous catalyst to oxidise the sulphide moiety. The present invention also relates to composites, methods of synthesising the composites and its use as a catalyst thereof.

Direct Decarboxylative Allylation and Arylation of Aliphatic Carboxylic Acids Using Flavin-Mediated Photoredox Catalysis

We describe herein a direct decarboxylative allylation of aliphatic carboxylic acids with allylsulfones using visible light and riboflavin tetraacetate (RFTA) as photocatalyst. The reaction proceeds at room temperature tolerating a wide range of functiona

Sulfinate-Organocatalyzed (3+2) Annulation Reaction of Propargyl or Allenyl Sulfones with Activated Imines

An operationally simple methodology for the synthesis of 4-sulfonyl-3-pyrrolines is described using a propargylic sulfone and N-sulfonyl imines as substrates. This annulation process is initiated by an arenesulfinate organocatalyst, which allows a smooth isomerization of the alkynyl precursor into the corresponding allene, followed by the generation of a highly reactive allyl sulfone anion. An asymmetric version involving an unprecedented enantiopure sulfinate–ammonium cooperative ion pair (PhSO2– R4N+*) was investigated. A proof-of-concept, with enantiomeric excesses of up to 41 %, was obtained according to a preliminary screening of commercially available chiral phase-transfer catalysts.