254730-12-6Relevant articles and documents
Asymmetric synthesis of (-)-(R)-pyrrolam A starting from (S)-malic acid
Huang, Pel Qiang,Chen, Quan Feng,Chen, Chang Lin,Zhang, Hong Kui
, p. 3827 - 3832 (2007/10/03)
An asymmetric synthesis of natural (-)-pyrrolam A starting from natural (S)-malic acid is described. The stereogenic center was established via a highly trans-diastereoselective reductive alkylation procedure. A tandem base-induced intramolecular amide N-