25660-58-6Relevant articles and documents
Preparation and N-alkylation of 4-Aryl-1,2,4-triazoles
Holm, Stefanie C.,Siegle, Alexander F.,Loos, Christian,Rominger, Frank,Straub, Bernd F.
experimental part, p. 2278 - 2286 (2010/08/20)
Heating of N,N-dimethylformamide azine dihydrochloride {N-[(dimethylamino) methylene]-N,N-dimethylhydrazonoformamide dihydrochloride} with anilines in the absence of a solvent gave a range of 4-aryl-1,2,4-triazoles by direct transamination. Ortho-substituents were tolerated. Some triazoles were converted into symmetrically and nonsymmetrically substituted bistriazolium salts, one of which was converted into a dicopper complex. Georg Thieme Verlag Stuttgart - New York.