2567-29-5

Basic information

• Product Name: 4-BROMOMETHYLBIPHENYL
• Synonyms: 4-BROMOMETHYLBIPHENYL;4-PHENYLBENZYL BROMIDE;4-Bromoethylbiphenyl;Bromoethylbiphenyl;1,1-Biphenyl, 4-(bromomethyl)-;Bromoethylbiphenyl 98%;4-BROMOMETHYLBIPHENYL 98+%;p-Phenylbenzyl bromide
• CAS NO: 2567-29-5
• Molecular Formula: C₁₃H₁₁Br
• Molecular Weight: 247.13
• Product Categories: Benzene series
• Mol File: 2567-29-5.mol
• Article Data: 1

Chemical Properties

• Melting Point: 83-86 °C
• Boiling Point: 140 °C / 10mmHg
• Flash Point: >110℃
• Appearance: Pale yellow to beige/Powder
• Density: 1.341 g/cm³
• Vapor Pressure: 0.000266mmHg at 25°C
• Refractive Index: 1.605
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: Chloroform, Methanol
• CAS DataBase Reference: 4-BROMOMETHYLBIPHENYL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMOMETHYLBIPHENYL(2567-29-5)
• EPA Substance Registry System: 4-BROMOMETHYLBIPHENYL(2567-29-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38-34
• Safety Statements: 37/39-26-45-36/37/39
• RIDADR: 3261
• HazardClass: IRRITANT
• Hazardous Substances Data: 2567-29-5(Hazardous Substances Data)

Usage

Uses

4-(Bromomethyl)biphenyl is a biphenyl derivative used in the preparation of various pharmaceutical compounds such as protein tyrosine phosphatase 1B inhibitors. 4-(Bromomethyl)biphenyl is useful as as atom transfer radical polymerization initiator.

InChI:InChI=1/C13H11Br/c14-10-11-6-8-13(9-7-11)12-4-2-1-3-5-12/h1-9H,10H2

Upstream product

• 589-15-1 1-bromomethyl-4-bromobenzene 
• 98-80-6 phenylboronic acid 
• 50-00-0 formaldehyd 
• 92-52-4 biphenyl 
• 10035-10-6 hydrogen bromide 
• 506-68-3 bromocyane 
• 861376-27-4 (4-ethyl-benzyl)-methyl-(4-phenyl-benzyl)-amine 
• 262371-18-6 1-([1,1’-biphenyl]-4-yl)-N-benzyl-N-methylmethanamine 

Downstream Products

• 124921-29-5 1-(4-biphenylylmethyl)-1-cyano-5-methoxy-1,2,3,4-tetrahydronaphthalene 
• 31603-77-7 4-biphenylacetonitrile 
• 139259-72-6 p-phenylbenzyl benzohydroxamate 
• 131227-62-8 Methyl 2-deoxy-2-(N,N-dimethylamino)-3,4,6-O-triphenylbenzyl-α-D-mannopyranoside 
• 131227-54-8 Methyl-2-deoxy-2-(N,N-dimethylamino)-3,4,6-O-triphenylbenzyl-α-D-glucopyranoside 
• 131227-58-2 Methyl 2-deoxy-2-(N,N-dimethylamino)-3,4,6-O-triphenylbenzyl-α-D-galactopyranoside 
• 131227-61-7 Methyl 2-deoxy-2-(N,N-dimethylamino)-4,6-O-diphenylbenzyl-3-O-methyl-α-D-mannopyranoside 
• 131227-53-7 Methyl 2-deoxy-2-(N,N-dimethylamino)-4,6-O-diphenylbenzyl-3-O-methyl-α-D-glucopyranoside 
• 131227-57-1 Methyl 2-deoxy-2-(N,N-dimethylamino)-4,6-O-diphenylbenzyl-3-O-methyl-α-D-galactopyranoside 
• 131227-56-0 Methyl 2-deoxy-2-(N,N-dimethylamino)-3,6-diphenylbenzyl-4-O-methyl-α-D-galactopyranoside 
• 131227-60-6 Methyl 2-deoxy-2-(N,N-dimethylamino)-3,6-O-diphenylbenzyl-4-O-methyl-α-D-mannopyranoside 
• 131227-52-6 Methyl 2-deoxy-2-(N,N-dimethylamino)-3,6-O-diphenylbenzyl-4-O-methyl-α-D-glucopyranoside 
• 86673-63-4 4-(5-Biphenyl-4-yl-3-phenyl-thiophen-2-yl)-morpholine 
• 115890-68-1 (3aR,4S,5R,7R,8aS)-7-(Biphenyl-4-ylmethoxy)-5-((S)-1,5-dimethyl-hex-4-enyl)-3-methyl-8-methylene-1,3a,4,5,6,7,8,8a-octahydro-azulen-4-ol 

Relevant articles and documents

Palladium(II) complexes of Y,C,Y-chelated phosphines: Synthesis, structure, and catalytic activity in Suzuki-Miyaura reaction

The phosphines L1PPh2 (1) and L2PPh 2 (2) containing different Y,C,Y-chelating ligands, L1 = 2,6-(tBuOCH2)2C6H3 - and L2 = 2,6-(Me2NCH2) 2C6H3-, were treated with PdCl 2 and di-Aμ-chloro-bis[2-[(N,N-dimethylamino)methyl]phenyl- C,N]-dipalladium(II) and yielded complexes trans-{[2,6-(tBuOCH 2)2C6H3]PPh2} 2PdCl2 (3), {[2,6-(Me2NCH2) 2C6H3]PPh2} PdCl2 (4), {[2,6-(tBuOCH2)2C6H 3]PPh2}Pd(Cl)[2-(Me2NCH2)C 6H4] (5) and {[2,6-(Me2NCH2) 2C6H3]PPh2}Pd(Cl)[2-(Me 2NCH2)C6H4] (6) as the result of different ability of starting phosphines 1 and 2 to complex PdCl2. Compounds 3-6 were characterized by 1H, 13C, 31P NMR spectroscopy and ESI-MS. The molecular structures of 3,4 and 6 were also determined by X-ray diffraction analysis. The catalytic activity of complexes 3-6 was evaluated in the Suzuki-Miyaura cross-coupling reaction.