25860-27-9

Basic information

• Product Name: anti-methyl 11,12-dioxatetracyclo[6.2.1.1^3,6.0^2,7.]dodeca-4.9-diene-2,7-dicarboxylate
• CAS NO: 25860-27-9
• Molecular Weight: 278.262
• Mol File: 25860-27-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: anti-methyl 11,12-dioxatetracyclo[6.2.1.1^3,6.0^2,7.]dodeca-4.9-diene-2,7-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: anti-methyl 11,12-dioxatetracyclo[6.2.1.1^3,6.0^2,7.]dodeca-4.9-diene-2,7-dicarboxylate(25860-27-9)
• EPA Substance Registry System: anti-methyl 11,12-dioxatetracyclo[6.2.1.1^3,6.0^2,7.]dodeca-4.9-diene-2,7-dicarboxylate(25860-27-9)

Safety Data

• Hazardous Substances Data: 25860-27-9(Hazardous Substances Data)

Upstream product

• 110-00-9 furan 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 625-86-5 2,5-dimethylfuran 

Downstream Products

• 95450-07-0 C₂₁H₁₉NO₇ 
• 95450-09-2 C₂₀H₁₈N₄O₈ 

Relevant articles and documents

Clay-catalyzed solventless addition reactions of furan with α,β- unsaturated carbonyl compounds

The reaction of furan with α,β-unsaturated carbonyl dienophiles catalyzed by K10 montmorillonite in the absence of organic solvents produces the corresponding Diels-Alder adducts and, in the case of methyl vinyl ketone, Michael-type products, under much milder conditions than the conventional protocols. The results are consistent with acid catalysis on the clay surface. Acrylates gave lower yields and/or decomposition products. The reaction can be extended to alkynic substrates such as DMAD to afford cycloadducts in good yields.