2696-95-9

Basic information

• Product Name: Cyclohexane, nitroso-
• CAS NO: 2696-95-9
• Molecular Formula: C6H11NO
• Molecular Weight: 113.159
• Mol File: 2696-95-9.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexane, nitroso-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, nitroso-(2696-95-9)
• EPA Substance Registry System: Cyclohexane, nitroso-(2696-95-9)

Safety Data

• Hazardous Substances Data: 2696-95-9(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
Cyclohexane, nitrosois used as a solvent in various chemical synthesis processes due to its ability to dissolve a wide range of substances. Its solubility properties make it a valuable component in the production of various chemical compounds.
Used in Rubber Chemical Production:
In the rubber industry, Cyclohexane, nitrosois utilized in the production of rubber chemicals. Its chemical properties contribute to the development of additives and other compounds that enhance the performance and characteristics of rubber products.
Used in Pharmaceutical Manufacturing:
Cyclohexane, nitrosoalso finds application in the pharmaceutical sector, where it is employed in the synthesis of certain drugs. Its versatility as a chemical intermediate allows for the creation of a variety of medicinal compounds.
Used in Research and Development:
Due to its unique chemical properties, Cyclohexane, nitrosois used in research and development settings to explore new applications and understand its behavior in different chemical reactions.

Upstream product

• 2211-64-5 N-cyclohexyl-hydroxylamine 
• 110-82-7 cyclohexane 

Downstream Products

• 4359-62-0 N,N'-dicyclohexylhydrazine 
• 2286-03-5 N-Cyclohexyl-N'-fluordiimid-N-oxid 
• 1646-26-0 1-(benzo[b]furan-2-yl)ethanone 

Relevant articles and documents

Unexpected Insertion of Nitrogen into a C-C Bond: Access to 2,3-Disubstituted Quinazolinone Scaffolds

A novel, practical, highly efficient, and transition metal free nitrogen insertion reaction for the synthesis of 2,3-disubstituted quinazolinone derivatives was developed. Diverse functionalized 3-indolinone-2-carboxylates and nitrosoarenes with a wide range of substituted nitrosobenzenes, nitrosopyridines, dibenzofuranyl, or dibenzothienyl nitroso compounds worked smoothly to give 2,3-disubstituted quinazolinone derivatives in good to excellent yields (69-98%). A gram-scale reaction was achieved, and an afloqualone analogue was synthesized under the mild reaction conditions.

METHOD FOR PRODUCING C4-C15 LACTAMS

The present invention relates to a process for preparing C4-C15 lactams, in which a C1-C10-alkyl nitrite is reacted with a C4-C15-cycloalkane and is illuminated with a light-emitting diode during the reaction. This forms a C4-C15-cyclohexanone oxime which is then converted further to a C4-C15 lactam; the C1-C10 alcohol formed is recycled into the preparation of the C1-C10-alkyl nitrite.

Mild and selective catalytic oxidation of organic substrates by a carbon nanotube-rhodium nanohybrid

A heterogeneous catalyst was assembled by stabilization of rhodium nanoparticles on carbon nanotubes. The nanohybrid was used for the catalytic aerobic oxidation of diverse substrates such as hydroquinones, hydroxylamines, silanes, hydrazines and thiols, at room temperature. The system proved very efficient on the investigated substrates and demonstrated high selectivity.

A new route to lactam precursors from cycloalkanes: Direct production of nitrosocycloalkanes or cycloalkanone oximes by using tert-Butyl nitrite and N-hydroxyphthalimide

Clean and selective: Nitrosation and oximation of cycloalkanes was achieved by treating them with tBuONO under Ar in the presente presence of a catalytic amount of N-hydroxyphthalimide (see scheme). The novel, clean nitrosation procedure uses halogen-free, relatively mild reaction conditions and results in good product selectivity (almost no organic byproducts) and high recovery of the catalyst.