2720-52-7

Basic information

• Product Name: 1-phenyl-
• CAS NO: 2720-52-7
• Molecular Weight: 158.2
• Mol File: 2720-52-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-(2720-52-7)
• EPA Substance Registry System: 1-phenyl-(2720-52-7)

Safety Data

• Hazardous Substances Data: 2720-52-7(Hazardous Substances Data)

Upstream product

• 14763-72-5 3-buten-1-ynylmagnesium bromide 
• 100-52-7 benzaldehyde 
• 593-60-2 Vinyl bromide 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 689-97-4 3-buten-1-yne 
• 7473-98-5 2-hydroxy-2-methylpropiophenone 

Downstream Products

• 1369534-35-9 (3,5,6-trivinylbenzene-1,2,4-triyl)tris(phenylmethanone) 
• 16278-55-0 1-phenylpent-4-en-2-yn-1-one 
• 93247-38-2 (3-methylpenta-1,2,4-trien-1-yl)benzene 
• 583-03-9 1-Phenyl-1-pentanol 
• 112564-73-5 (2E)-1-phenyl-2,4-pentadiene-1-ol 

Relevant articles and documents

Fe-Catalyzed Selective Cyclopropanation of Enynes under Photochemical or Thermal Conditions

The nucleophilic Fe-complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the cyclopropanation of enynes to substituted propargyl cyclopropanes using diazoesters as carbene surrogates. The catalyst can be activated either thermally in the presence of catalytic amounts of 4-nitroanisole or under photochemical conditions. Cyclopropanation occurs selectively at the enyne moiety; alternative olefinic moieties remain intact.

Triple-Bond Insertion Triggers Highly Regioselective 1,4-Aminomethylamination of 1,3-Enynes with Aminals Enabled by Pd-Catalyzed C-N Bond Activation

A highly chemo- and regioselective 1,4-aminomethylamination of simple enynes with aminals to allenic 1,5-diamines by taking advantage of C-N bond activation has been reported. The reaction proceeds under mild reaction conditions and can be performed under

Regioselective solvent-dependent benzannulation of conjugated enynes

The transformation of enynes under cobalt-catalysis leads to symmetrical benzannulation products in dichloromethane. In tetrahydrofuran the cobalt-catalysed reactions afforded the unprecedented unsymmetrical benzannulation products in moderate to good yields and good regioselectivities. In addition, cyclotrimerisation of the alkyne subunit can be realised when electron-deficient enynes are applied in the cobalt-catalysed transformations to generate 1,2,4-trivinylbenzene derivatives using tetrahydrofuran as solvent.