27415-42-5Relevant articles and documents
Facile generation of a strained cyclic vinyl cation by thermal solvolysis of cyclopent-1-enyl-λ3-bromanes
Miyamoto, Kazunori,Shiro, Motoo,Ochiai, Masahito
supporting information; experimental part, p. 8931 - 8934 (2010/02/28)
Last of the cyclic vinyl cations: The simple solvolysis of cyclopent-1 -enyl-13-bromane efficiently generates the highly strained cyclopent-1 -enyl cation at room temperature (see scheme). The very high nucleofugality of the aryl-13-bromanyl groups are re