2819-12-7

Basic information

• Product Name: 3-(phenylthio)-2-methylcyclopentanone
• Synonyms: 3-(phenylthio)-2-methylcyclopentanone
• CAS NO: 2819-12-7
• Molecular Weight: 174.243
• Mol File: 2819-12-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 3-(phenylthio)-2-methylcyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(phenylthio)-2-methylcyclopentanone(2819-12-7)
• EPA Substance Registry System: 3-(phenylthio)-2-methylcyclopentanone(2819-12-7)

Safety Data

• Hazardous Substances Data: 2819-12-7(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 13866-28-9 2,2-dichloro-3-phenylcyclobutanone 
• 74-88-4 methyl iodide 
• 1120-73-6 2-methyl-2-cyclopenten-1-one 
• 98-80-6 phenylboronic acid 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 80586-92-1 [(E)-3-(prop-2-enyloxy)-propenyl]benzene 
• 42436-86-2 2-phenylcyclobutanone 
• 106987-90-0 1-chloro-2-(ethylsulfinyl)benzene 
• 108-86-1 bromobenzene 
• 1541-32-8 2-methylcyclopent-1-en-1-yl acetate 
• 1821-12-1 4-Phenylbutyric acid 
• 18496-54-3 phenylbutyric acid chloride 
• 83187-70-6 2-Diazo-6-phenylhexan-3-one 

Downstream Products

• 57374-45-5 1-Acetoxy-2-methyl-3-phenyl-cyclopenten 
• 26029-34-5 2-methyl-3-phenyl-2-cyclopentenone 

Relevant articles and documents

Asymmetric Michael addition reactions using a chiral La-Na aminodiolate catalyst

(R,R)-(+)-2-[Benzyl-(2-hydroxy-2-phenylethyl)amino]-1-phenylethanol 1 is used as a chiral ligand in the synthesis of an optically active lanthanum-sodium amino diol complex LS-1. This heterobimetallic catalyst is quite effective as an asymmetric catalyst for various Michael addition reactions, 1H NMR study indicates the co-ordination of enone to the central lanthanum atom in LS-1. The reaction conditions were optimized and the adducts were obtained in high yield with moderate to high enantiomeric excess under extremely mild conditions.

Selective C-C Bond Scission of Ketones via Visible-Light-Mediated Cerium Catalysis

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Rhodium-catalyzed olefin isomerization/allyl claisen rearrangement/ intramolecular hydroacylation cascade

It has been established that a cationic Rh(I)/dppf complex catalyzes the olefin isomerization/allyl Claisen rearrangement/intramolecular hydroacylation cascade of di(allyl) ethers to produce substituted cyclopentanones in good yields under mild conditions.