2883-05-8Relevant articles and documents
Thermal Addition of Alkanes to Alkenes. V. Addition of Cyclohexane to 1-Octene in a Free Radical Chain reaction at Supercritical Fluid Conditions
Metzger, Juergen O.
, p. 767 - 781 (2007/10/02)
Alkanes can be added to alkenes in a thermally initiated free radical chain reaction ("ane reaction").Kinetic and mechanistic studies on the addition of cyclohexane (1) to 1-octene (2) (molar ratio = 100:1) at 330-450 deg C and pressures of up to 300 bar
HOCHDRUCK-HOCHTEMPERATUR-REAKTIONEN IN EINEM STROEMUNGSREAKTOR-VI. THERMISCHE ADDITION VON ALKANEN AN ALKENE
Metzger, Juergen,Hartmanns, Joerg,Koell, Peter
, p. 1891 - 1894 (2007/10/02)
The thermal Anti-Markownikow-addition of alkanes to activated and desactivated alkenes ("direkte substituierende Addition", "Ane-reaction") at 650-723 K and reaction times of 1-10 min. is described.