2919-12-2

Basic information

• Product Name: Benzenamine,2,4,6-trinitro-N-phenyl-
• Synonyms: Diphenylamine,2,4,6-trinitro- (6CI,7CI,8CI); 1-Anilino-2,4,6-trinitrobenzene;2,4,6-Trinitro-1-(phenylamino)benzene; 2,4,6-Trinitrodiphenylamine;N-(2,4,6-Trinitrophenyl)aniline; N-Phenylpicramide; N-Picrylaniline;Phenyl(2,4,6-trinitrophenyl)amine; Picranilide
• CAS NO: 2919-12-2
• Molecular Formula: C12H8 N4 O6
• Molecular Weight: 304.219
• Mol File: 2919-12-2.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 445.06°C (rough estimate)
• Density: 1.4549 (rough estimate)
• Refractive Index: 1.6081 (estimate)
• Water Solubility: 17.91mg/L(25 oC)
• CAS DataBase Reference: Benzenamine,2,4,6-trinitro-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine,2,4,6-trinitro-N-phenyl-(2919-12-2)
• EPA Substance Registry System: Benzenamine,2,4,6-trinitro-N-phenyl-(2919-12-2)

Safety Data

• Hazardous Substances Data: 2919-12-2(Hazardous Substances Data)

Upstream product

• 88-88-0 2,4,6-trinitrochlorobenzene 
• 64-17-5 ethanol 
• 538-51-2 benzylidene phenylamine 
• 88-89-1 2,4,6-Trinitrophenol 
• 606-35-9 1-methoxy-2,4,6-trinitrobenzene 
• 62-53-3 aniline 
• 67-66-3 chloroform 
• 60-29-7 diethyl ether 
• 1600-31-3 2-azido-1,3,5-trinitro-benzene 
• 857592-15-5 N-methyl-2,4,6-trinitro-N-nitroso-aniline 
• 14677-67-9 phenyl-picryl sulfone 
• 6641-62-9 picryl-o-tolyl ether 
• 74534-05-7 picryl-m-tolyl ether 
• 903-94-6 2,4-dimethylphenyl 2,4,6-trinitrophenyl ether 

Downstream Products

• 21565-22-0 (2,4-dinitro-phenyl)-picryl-amine 
• 131-73-7 Dipikrylamin 
• 50892-90-5 5,7-dinitro-1-(2',4',6'-trinitrophenyl)benzotriazole 
• 105049-00-1 5,7-dinitro-1-phenylbenzotriazole 
• 105049-02-3 1-(2',4'-dinitrophenyl)-5,7-dinitrobenzotriazole 
• 105049-01-2 5,7-dinitro-1-(4'-nitrophenyl)benzotriazole 
• 38229-29-7 2,4,6,2'-tetranitrodiphenylamine 
• 38417-97-9 N-(p-nitrophenyl)picrylamine 
• 105048-99-5 2-amino-4,6-dinitrodiphenylamine 
• 62902-40-3 2,6-dichloro-4-iodo-2',4',6'-trinitrodiphenylamine 

Relevant articles and documents

Anilinolysis of nitro-substituted diphenyl ethers in acetonitrile: the effect of some ortho-substituents on the mechanism of SNAr reactions

Rate data are reported for the reactions of a series of X-phenyl 2,4,6-trinitrophenyl ethers 1a-e [X = H, 4-NO2,2-NO2, 2,4-(NO2)2, or 2,6-(NO2)2] with substituted anilines 2a-e [Y = H, 2-CH

Modification of the Order of Reaction and Reaction Rate of Nucleophilic Aromatic Substitution in Micellar Solutions

The rate of formation of 2,4,6-trinitrodiphenylamine following the attack of aniline on 1-methoxy-2,4,6-trinitrobenzene has been studied in micellar media.The partial order with reference to the nucleophilic reagent (aniline) is unity in solutions of cationic detergents (positive micelles) and 3/2 in water or solutions of anionic detergents.For such reactions there are two main steps in the reaction scheme: first, the formation of an adduct between reagents, favoured by the effect of local higher concentration in the two kinds of micellar solutions and secondly, ejection of a proton from the adduct formed.The latter reaction is catalysed largely by positive micelles and in this case the kinetics are not limited by the deprotonation step.On the other hand, negative micelles inhibit the ejection of a proton and this opposes, in part, the effect of higher local concentrations.

The synthesis of vinylogous amidine heterocycles

We report herein a convenient synthetic methodology for the conversion of meta-dinitro heterocyclic rings to iminoquinones with vinylogous amidine functionality. These structures are found in nature, particularly in marine organisms, and may be important

The influence of some steric and electron effects on the mechanism of aromatic nucleophilic substitution (SNAr) reactions in nonpolar solvent

Kinetic studies are reported for the reactions with aniline in benzene of a series of X-phenyl 2,4,6-trinitrophenyl ethers [X = H; 2-, 3-, 4-CH 3; 2,4-, or 2,6-(CH3)2] 1a-f, and the results compared with those of the corre