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29858-07-9

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29858-07-9 Usage

Chemical Properties

off-white to to beige crystalline powder/chunks

Uses

Different sources of media describe the Uses of 29858-07-9 differently. You can refer to the following data:
1. The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.
2. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene.

Check Digit Verification of cas no

The CAS Registry Mumber 29858-07-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,9,8,5 and 8 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 29858-07:
(7*2)+(6*9)+(5*8)+(4*5)+(3*8)+(2*0)+(1*7)=159
159 % 10 = 9
So 29858-07-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H10O.2BrH.Mg/c1-3-5-4-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

29858-07-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail
  • Alfa Aesar

  • (L15481)  Magnesium bromide diethyl etherate, 98%   

  • 29858-07-9

  • 25g

  • 470.0CNY

  • Detail
  • Aldrich

  • (225959)  Magnesiumbromideethyletherate  99%

  • 29858-07-9

  • 225959-25G

  • 518.31CNY

  • Detail
  • Aldrich

  • (225959)  Magnesiumbromideethyletherate  99%

  • 29858-07-9

  • 225959-100G

  • 1,546.74CNY

  • Detail

29858-07-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name magnesium,ethoxyethane,dibromide

1.2 Other means of identification

Product number -
Other names magnesium bromide diethyl etherate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:29858-07-9 SDS

29858-07-9Relevant articles and documents

Stereoselective Synthesis of the C1-C9 and C11-C25 Fragments of Amphidinolides C, C2, C3, and F

Akwaboah, Daniel C.,Wu, Dimao,Forsyth, Craig J.

supporting information, p. 1180 - 1183 (2017/03/14)

An efficient synthesis of the C1-C9 and the C11-C25 fragments of amphidinolides C, C2, C3, and F from a common intermediate is reported. The construction of the C1-C9 fragment involves an intramolecular hetero-Michael cyclization to form the 3,5-disubstituted trans-tetrahydrofuran moiety. The approach to prepare the C11-C25 fragment utilizes a highly stereoselective aerobic cobalt-catalyzed alkenol cyclization and a chelated Mukaiyama aldol reaction to form the C13-C14 bond and to concomitantly install the C13 hydroxyl group.

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