30224-53-4

Basic information

• Product Name: bis(diphenylstibino)methane
• Synonyms: bis(diphenylstibino)methane
• CAS NO: 30224-53-4
• Molecular Weight: 565.95
• Mol File: 30224-53-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(diphenylstibino)methane(CAS DataBase Reference)
• NIST Chemistry Reference: bis(diphenylstibino)methane(30224-53-4)
• EPA Substance Registry System: bis(diphenylstibino)methane(30224-53-4)

Safety Data

• Hazardous Substances Data: 30224-53-4(Hazardous Substances Data)

Upstream product

• 2629-47-2 diphenylantimony(III) chloride 
• 591-50-4 iodobenzene 
• 32278-97-0 bis(dichlorostibino)methane 
• 108-86-1 bromobenzene 
• 186581-53-3 diazomethane 
• 2654-44-6 tetraphenyldistibane 
• 603-36-1 triphenylantimony 
• 74-95-3 1,1-dibromomethane 
• 199176-25-5 Ni(CO)3(η(1)-bis(diphenylstibino)methane) 

Downstream Products

• 52393-26-7 Mo(CO)2I₂{(C₆H₅)2Sb}2CH₂ 
• 52393-16-5 Mo(CO)3I₂{(C₆H₅)2Sb}2CH₂ 
• 199176-25-5 Ni(CO)3(η(1)-bis(diphenylstibino)methane) 
• 199176-26-6 Ni2(CO)6(μ-bis(diphenylstibino)methane) 
• 58284-59-6 Ph₂Sb(n-Bu) 
• 38073-47-1 methylethylphenylstibine 
• 17585-86-3 dimethyl(phenyl)stibine 
• 38073-50-6 (C₆H₅)(CH₃)Sb(i-C₃H₇) 
• 70367-15-6 {(diphenylstibino)methyl}copper(I) 
• 33756-92-2 (C₆H₅)2(CH₃)SbF₂ 
• 38073-48-2 benzylmethylphenylstibine 
• 38611-85-7 (C₆H₅)2(CH₃)SbBr₂ 
• 38611-47-1 bis(methylphenylstibino)methane 
• 38611-77-7 {(C₆H₅)(CH₃)Sb}2(CH₂)3 

Relevant articles and documents

REACTIVITY OF MOLECULES CONTAINING ELEMENT-ELEMENT BONDS. PART III. REDUCTION OF HALO-ORGANOMETALLICS OF ANTIMONY(III) AND BISMUTH(III); CRYSTAL AND MOLECULAR STRUCTURE OF CoCp2

Tetraphenyldibismuthine has been prepared by reducing BiPh2I with bis (cyclopentadienyl)-cobalt(II).CoCp2, the former being produced in situ in THF solution from BiPh3 and BiI3 (2:1 molar ratio) or from BiPh3 and I2; also, bis(pentamethylcyclopentadienyl)cobalt(II), CoCp2, reduces BiPh2Cl to Bi2Ph4 in THF solution.The bismuth(III) bromides Bi(p-tolyl)2Br or BiMe2Br have been reduced by CoCp2 to the corresponding dibismuthines, Bi2(p-tolyl)4 or Bi2Me4.Reduction by CoCp2 of the chloro derivatives of bismuth(III) and antimony(III), EPh2Cl produces E2Ph4 and the ionic CoCp2 complexes as by-products.The crystal and molecular structure of the antimony derivative CoCp2 was solved by X-ray diffraction methods.Crystal data: monoclinic, space group P21, a = 8.856(3), b = 16.245(5), c = 7.770(3) Angstroem, β = 109.67(5) deg, Z = 2, R = 0.0396.Similar to Bi2Ph4, Sb2Ph4 undergoes reactions across the element-element bond with p-benzoquinone and diazomethane to the corresponding insertion products (Ph2Sb)2O2C6H4 and (Ph2Sb)2CH2, respectively.