307554-62-7Relevant articles and documents
New reagents for determination of the quantum efficiency of singlet oxygen generation in aqueous media
Kuznetsova,Gretsova,Yuzhakova,Negrimovskii,Kaliya,Luk'yanets
, p. 36 - 41 (2001)
Water-soluble anthracene derivatives containing carboxy, dihydroxyphosphinyl, or pyridinium fragments bound via methylene groups to 9- and 10-carbon atoms were prepared, and their spectra, solubility, and reactivity toward singlet oxygen were studied. Using sodium α,α1-(anthracene-9,10-diyl)bis(methylmalonate) as acceptor, it is possible to determine the quantum efficiency of singlet oxygen generation in aqueous solutions and in microheterogeneous media in the presence of biomacromolecules.
Synthetic β-Cyclodextrin Dimers for Squaraine Binding: Effect of Host Architecture on Photophysical Properties, Aggregate Formation and Chemical Reactivity
Chaudhuri, Sauradip,Verderame, Molly,Mako, Teresa L.,Bandara, Y. M. Nuwan D. Y.,Fernando, Ashvin I.,Levine, Mindy
, p. 1964 - 1974 (2018/05/15)
Reported herein is the synthesis and application of three novel β-cyclodextrin dimer hosts for the complexation of near infrared (NIR) squaraine dyes in aqueous solution. A series of eight different N-substituted N-methyl anilino squaraine dyes with variable terminal groups are investigated, with an optimal n-hexyl-substituted squaraine guest demonstrating binding constants orders of magnitude higher than the other squaraine–host combinations and comparable to literature-reported systems. Moreover, hydrophobic complexation of the squaraine dyes with the β-cyclodextrin dimer hosts causes drastic changes in the squaraine's photophysical properties, propensity for aggregation and susceptibility to hydrolytic decay.
Synthesis of a hydrophilic and non-ionic anthracene derivative, the N,N′-di-(2,3-dihydroxypropyl)-9,10-anthracenedipropanamide as a chemical trap for singlet molecular oxygen detection in biological systems
Martinez, Glaucia R.,Garcia, Flávia,Catalani, Luiz H.,Cadet, Jean,Oliveira, Mauricio C.B.,Ronsein, Graziella E.,Miyamoto, Sayuri,Medeiros, Marisa H.G.,Mascio, Paolo Di
, p. 10762 - 10770 (2007/10/03)
We report herein the synthesis of a new hydrophilic and non-ionic anthracene derivative, the N,N′-di-(2,3-dihydroxypropyl)-9,10-anthracenedipropanamide. The evaluation of this compound as chemical trap of singlet molecular oxygen by using labeling experiments and HPLC-MS analysis showed that it could be efficiently used in biological investigations.