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3121-61-7

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3121-61-7 Usage

Chemical Properties

clear colorless to slightly yellow liquid

General Description

Clear colorless liquid with a sharp musty odor.

Air & Water Reactions

Water soluble.

Reactivity Profile

2-Methoxyethyl acrylate is sensitive to heat and light. Incompatible with strong oxidizing agents and polymerization initiators .

Fire Hazard

2-Methoxyethyl acrylate is combustible.

Flammability and Explosibility

Flammable

Safety Profile

Poison by skin contact. Moderately toxic by ingestion and inhalation. Experimental reproductive effects. A skin irritant. Flammable when exposed to heat or flame; can react with oxidlzing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

Check Digit Verification of cas no

The CAS Registry Mumber 3121-61-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,1,2 and 1 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 3121-61:
(6*3)+(5*1)+(4*2)+(3*1)+(2*6)+(1*1)=47
47 % 10 = 7
So 3121-61-7 is a valid CAS Registry Number.
InChI:InChI=1/C6H10O3/c1-3-6(7)9-5-4-8-2/h3H,1,4-5H2,2H3

3121-61-7 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail
  • Alfa Aesar

  • (L11902)  2-Methoxyethyl acrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol   

  • 3121-61-7

  • 50g

  • 191.0CNY

  • Detail
  • Alfa Aesar

  • (L11902)  2-Methoxyethyl acrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol   

  • 3121-61-7

  • 250g

  • 400.0CNY

  • Detail
  • Alfa Aesar

  • (L11902)  2-Methoxyethyl acrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol   

  • 3121-61-7

  • 1000g

  • 1077.0CNY

  • Detail
  • Aldrich

  • (408913)  Ethyleneglycolmethyletheracrylate  contains 50-100 ppm MEHQ as inhibitor, 98%

  • 3121-61-7

  • 408913-250ML

  • 393.12CNY

  • Detail
  • Aldrich

  • (408913)  Ethyleneglycolmethyletheracrylate  contains 50-100 ppm MEHQ as inhibitor, 98%

  • 3121-61-7

  • 408913-1L

  • 1,396.98CNY

  • Detail

3121-61-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methoxyethyl prop-2-enoate

1.2 Other means of identification

Product number -
Other names Ethylene Glycol Monomethyl Ether Acrylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Functional fluids (closed systems)
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3121-61-7 SDS

3121-61-7Synthetic route

2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

Conditions
ConditionsYield
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature; Solvent;95%
With copper; toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Methanols als Azeotrop mit Methylacrylat;
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

ethyl acrylate
140-88-5

ethyl acrylate

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

Conditions
ConditionsYield
With copper; toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Aethanols als Azeotrop mit Aethylacrylat;
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

acryloyl chloride
814-68-6

acryloyl chloride

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

Conditions
ConditionsYield
With triethylamine In chloroform at 10℃; for 12h;
In dichloromethane
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

bis((methyldiethoxysilyl)propyl)amine
31020-47-0

bis((methyldiethoxysilyl)propyl)amine

2-methoxyethyl 3-(bis(3-diethoxymethylsilylpropyl)amino)propanoate

2-methoxyethyl 3-(bis(3-diethoxymethylsilylpropyl)amino)propanoate

Conditions
ConditionsYield
In ethanol at 20℃; for 8h; Inert atmosphere;98.327%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

bis-(3-triethoxysilylpropyl)amine
13497-18-2

bis-(3-triethoxysilylpropyl)amine

2-methoxyethyl 3-(bis(3-triethoxysilylpropyl)amino)propanoate

2-methoxyethyl 3-(bis(3-triethoxysilylpropyl)amino)propanoate

Conditions
ConditionsYield
In ethanol at 20℃; for 8h; Inert atmosphere;97.3%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

thiophenol
108-98-5

thiophenol

3-phenylsulfanyl-propionic acid butyl ester

3-phenylsulfanyl-propionic acid butyl ester

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In neat (no solvent) at 20℃; for 2h; Green chemistry; regioselective reaction;97%
(N-cyclohexylaminomethyl)triethoxysilane

(N-cyclohexylaminomethyl)triethoxysilane

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

2-methoxyethyl 3-(cyclohexyl((triethoxysilyl)methyl)amino)propanoate

2-methoxyethyl 3-(cyclohexyl((triethoxysilyl)methyl)amino)propanoate

Conditions
ConditionsYield
In ethanol at 20℃; for 8h; Inert atmosphere;96.7%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

1-Methyl-1-phenylhydrazine
618-40-6

1-Methyl-1-phenylhydrazine

(E)-2-methoxyethyl 3-(2-(methylamino)phenyl)acrylate

(E)-2-methoxyethyl 3-(2-(methylamino)phenyl)acrylate

Conditions
ConditionsYield
With [RhCl2(p-cymene)]2; potassium acetate In methanol at 70℃; Sealed tube;96%
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; acetic acid In methanol at 25℃; for 6h;91%
ethanol
64-17-5

ethanol

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

1,3-diphenylpropanedione
120-46-7

1,3-diphenylpropanedione

ethyl 4-benzoylbutanoate
73172-56-2

ethyl 4-benzoylbutanoate

Conditions
ConditionsYield
With potassium carbonate at 85℃; Sealed tube;95%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

1-iodosinomenine
945761-25-1

1-iodosinomenine

C25H31NO7

C25H31NO7

Conditions
ConditionsYield
With palladium diacetate; triethylamine; triphenylphosphine In N,N-dimethyl-formamide at 85℃; for 0.333333h; Time; Heck Reaction;93%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

diphenyl acetylene
501-65-5

diphenyl acetylene

2-methoxyethyl (2E,4Z)-4,5-diphenylpenta-2,4-dienoate
1644664-66-3

2-methoxyethyl (2E,4Z)-4,5-diphenylpenta-2,4-dienoate

Conditions
ConditionsYield
With C34H32N2Ru In toluene at 20 - 22℃; for 24h; Inert atmosphere;93%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

(1E,4E)-1,5-di-p-tolylpenta-1,4-dien-3-one O-isopropyl oxime

(1E,4E)-1,5-di-p-tolylpenta-1,4-dien-3-one O-isopropyl oxime

2-methoxyethyl (E)-6-(4-methylstyryl)-4-(p-tolyl)picolinate

2-methoxyethyl (E)-6-(4-methylstyryl)-4-(p-tolyl)picolinate

Conditions
ConditionsYield
With palladium diacetate; silver trifluoroacetate; 2,6-bis(((3S,5S,7S)-adamantan-1-yl)oxy)pyridine In 1,4-dioxane at 90℃; for 24h; regioselective reaction;93%
4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

acrylic acid 2-oxo-[1,3]dioxolan-4-ylmethyl ester
7528-90-7

acrylic acid 2-oxo-[1,3]dioxolan-4-ylmethyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacrylate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 90 - 760 Torr; for 20h; Catalytic behavior; Reagent/catalyst; Pressure;92%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

Pentafluorobenzene
363-72-4

Pentafluorobenzene

C12H11F5O3
1226635-89-7

C12H11F5O3

Conditions
ConditionsYield
With [Rh(OH)(cod)]2; o-phenylenebis(diphenylphosphine); water In 1,4-dioxane at 120℃; for 24h; Inert atmosphere;91%
furfural
98-01-1

furfural

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

3-(2-furyl)-3-hydroxy-2-methylene-propanoic acid 2-methoxyethyl ester
144261-84-7

3-(2-furyl)-3-hydroxy-2-methylene-propanoic acid 2-methoxyethyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane for 36h; Ambient temperature;90%
1-benzopyran-4(4H)-one
491-38-3

1-benzopyran-4(4H)-one

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

(E)-methoxyethyl 3-(4-oxo-4H-chromen-5-yl)acrylate

(E)-methoxyethyl 3-(4-oxo-4H-chromen-5-yl)acrylate

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; silver(I) acetate; silver(I) triflimide In 1,2-dichloro-ethane at 20 - 120℃; for 1h; Sealed tube;90%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

benzaldehyde
100-52-7

benzaldehyde

3-phenyl-3-hydroxy-2-methylene-propanoic acid 2-methoxyethyl ester
144261-74-5

3-phenyl-3-hydroxy-2-methylene-propanoic acid 2-methoxyethyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane for 96h; Ambient temperature;89%
tert-Butylacetic acid
1070-83-3

tert-Butylacetic acid

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

2-methoxyethyl 2-(4,4-dimethyl-6-oxotetrahydro-2H-pyran-2-yl)acetate

2-methoxyethyl 2-(4,4-dimethyl-6-oxotetrahydro-2H-pyran-2-yl)acetate

Conditions
ConditionsYield
With disodium phosphate heptahydrate; (S)-2-acetylamino-3-phenylpropanoic acid; palladium diacetate; silver carbonate at 120℃; for 18h; Sealed tube;88%
2-phenyl-indole
948-65-2

2-phenyl-indole

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

(2E,2'E)-bis(2-methoxyethyl) 3,3'-(2-(1H-indol-2-yl)-1,3-phenylene)diacrylate

(2E,2'E)-bis(2-methoxyethyl) 3,3'-(2-(1H-indol-2-yl)-1,3-phenylene)diacrylate

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate In ethyl acetate at 140℃; for 24h; Inert atmosphere; Schlenk technique; regioselective reaction;86%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

benzoyltrimethylsilane
5908-41-8

benzoyltrimethylsilane

2-methoxyethyl (E)-3-(2-((trimethylsilyl)carbonyl)phenyl)acrylate

2-methoxyethyl (E)-3-(2-((trimethylsilyl)carbonyl)phenyl)acrylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper diacetate In 1,2-dichloro-ethane at 60℃; for 24h; Sealed tube; Inert atmosphere; Enzymatic reaction;86%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

thiophenol
108-98-5

thiophenol

2-methoxyethyl 3-(phenylthio)propionate

2-methoxyethyl 3-(phenylthio)propionate

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In neat (no solvent) at 20℃; for 3h; Green chemistry; regioselective reaction;85%
1,3-dimethyluracil
874-14-6

1,3-dimethyluracil

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

(E)-2-methoxyethyl 3-(1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)acrylate

(E)-2-methoxyethyl 3-(1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)acrylate

Conditions
ConditionsYield
With N-Cbz-L-Phe; oxygen; palladium diacetate; Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; under 760.051 Torr; for 24h; Heck Reaction; Schlenk technique; Green chemistry;85%
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

2-methoxyethyl 2-(4-methyl-3-oxo-1,3-dihydroisobenzofuran-1-yl)acetate

2-methoxyethyl 2-(4-methyl-3-oxo-1,3-dihydroisobenzofuran-1-yl)acetate

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; oxygen; potassium acetate; acetic acid at 80℃; under 760.051 Torr; for 18h; Green chemistry; chemoselective reaction;85%
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; potassium acetate; p-benzoquinone In tert-Amyl alcohol; water at 100℃; for 18h; Electrolysis; chemoselective reaction;84%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

1,4-butanediol monoglycidyl ether
4711-95-9

1,4-butanediol monoglycidyl ether

4-Hydroxybutyl acrylate glycidyl ether
119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

Conditions
ConditionsYield
With tetrabutoxytitanium; 4-methoxy-phenol In o-xylene at 80 - 90℃; under 75.0075 Torr;83.7%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

C14H27NSi2

C14H27NSi2

C20H31NO6

C20H31NO6

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium dichloride In N,N-dimethyl-formamide at 25℃; for 12h; Schlenk technique; Sealed tube; Glovebox; Inert atmosphere; Irradiation;83%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

2-methoxyethyl 2-iodoacrylate
1422263-07-7

2-methoxyethyl 2-iodoacrylate

Conditions
ConditionsYield
With N-iodophthalimide; 3-quinuclidinol In acetonitrile at 20℃; for 24h; Darkness; chemoselective reaction;82%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

1,3-diphenylpropanedione
120-46-7

1,3-diphenylpropanedione

2-methoxyethyl 5-oxo-5-phenylpentanoate

2-methoxyethyl 5-oxo-5-phenylpentanoate

Conditions
ConditionsYield
With potassium carbonate at 85℃; Sealed tube;80%
With potassium carbonate In 2-methoxy-ethanol at 85℃; for 24h;80%
pyrrolidine
123-75-1

pyrrolidine

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

phenylglyoxal hydrate
1074-12-0

phenylglyoxal hydrate

2-methoxyethyl 5-benzoyl-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-pyrrolizine-7-carboxylate

2-methoxyethyl 5-benzoyl-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-pyrrolizine-7-carboxylate

Conditions
ConditionsYield
With acetic acid In toluene at 100℃; for 0.666667h;80%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

phenol
108-95-2

phenol

2-methoxyethyl (E)-3-phenoxyacrylate

2-methoxyethyl (E)-3-phenoxyacrylate

Conditions
ConditionsYield
With tetrabutylammomium bromide; oxygen; palladium diacetate; potassium carbonate In dichloromethane at 40℃; for 36h; Schlenk technique;80%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

2-(cyclohex-2-en-1-yloxy)-1,10-phenanthroline

2-(cyclohex-2-en-1-yloxy)-1,10-phenanthroline

2-methoxyethyl (E)-3-(6-((1,10-phenanthrolin-2-yl)oxy)cyclohex-1-en-1-yl)acrylate

2-methoxyethyl (E)-3-(6-((1,10-phenanthrolin-2-yl)oxy)cyclohex-1-en-1-yl)acrylate

Conditions
ConditionsYield
With 2-methyl-2-phenylpropionic acid; palladium diacetate; silver trifluoroacetate; p-benzoquinone In acetonitrile at 50℃; under 760.051 Torr; for 22h; Sealed tube; regioselective reaction;79%
3-hexen-1-ol
544-12-7

3-hexen-1-ol

2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

C12H20O4

C12H20O4

Conditions
ConditionsYield
With 2,2,2-trifluoroethanol; (S)-2-acetylamino-3-phenylpropanoic acid; palladium diacetate; caesium carbonate; silver carbonate In 1,4-dioxane at 70℃; for 16h; Inert atmosphere;78%
2-methoxyethyl acrylate
3121-61-7

2-methoxyethyl acrylate

α-(Fluorophenyl)acetonitrile
10036-43-8

α-(Fluorophenyl)acetonitrile

2-methoxyethyl 4-cyano-4-fluoro-4-phenylbutanoate

2-methoxyethyl 4-cyano-4-fluoro-4-phenylbutanoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dimethyl sulfoxide at 25℃; Catalytic behavior; Solvent; Michael Addition;76%

3121-61-7Relevant articles and documents

Ruthenium(II) oxidase catalysis for C-H alkenylations in biomass-derived γ-valerolactone

Bechtoldt, Alexander,Baumert, Marcel E.,Vaccaro, Luigi,Ackermann, Lutz

supporting information, p. 398 - 402 (2018/02/07)

Ruthenium(ii) biscarboxylate oxidase catalysis is a powerful tool for the assembly of functionalized arenes with oxygen as a green oxidant, but this strategy was thus far limited to its use in traditional organic solvents. Herein, we report on a green procedure for the ruthenium(ii) biscarboxylate-catalysed C-H functionalisation in biomass-derived γ-valerolactone as the reaction medium. The oxidase catalysis was characterized by ample substrate scope and proceeded efficiently with oxygen as the sole oxidant. The overall green nature of this C-H-activation methodology is reflected by H2O being the only by-product.

The 'Baylis - Hillman reaction' mechanism and applications revisited

Fort, Yves,Berthe, Marie Christine,Caubere, Paul

, p. 6371 - 6384 (2007/10/02)

It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

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