31915-94-3

Basic information

• Product Name: cis-1,3-Butadienylbenzene.
• Synonyms: cis-1,3-Butadienylbenzene.
• CAS NO: 31915-94-3
• Molecular Formula: C₁₀H₁₀
• Molecular Weight: 130.1864
• Mol File: 31915-94-3.mol
• Article Data: 48

Chemical Properties

• Melting Point: -57°C
• Boiling Point: 175.9°C (rough estimate)
• Flash Point: 70.8°C
• Appearance: /
• Density: 0.9334
• Vapor Pressure: 0.355mmHg at 25°C
• Refractive Index: 1.6095
• CAS DataBase Reference: cis-1,3-Butadienylbenzene.(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,3-Butadienylbenzene.(31915-94-3)
• EPA Substance Registry System: cis-1,3-Butadienylbenzene.(31915-94-3)

Safety Data

• Hazardous Substances Data: 31915-94-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H10/c1-2-3-7-10-8-5-4-6-9-10/h2-9H,1H2/b7-3-

Upstream product

• 18221-40-4 (4ar,8at)-4a,8a-dihydro-naphthalene 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 97072-45-2 1-((E)-1-phenylbuta-1,3-dien-2-ylsulfonyl)benzene 
• 57918-63-5 (Z)-styryl iodide 
• 4627-10-5 4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane 
• 588-73-8 (Z)-β-bromostyrene 
• 75927-49-0 pinacol vinylboronate 
• 1515-78-2 buta-1,3-dien-1-ylbenzene 
• 694-53-1 phenylsilane 
• 104-51-8 1-butylbenzene 
• 100-52-7 benzaldehyde 
• 94397-40-7 (1-bromoallyl)trimethylsilane 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 1560-54-9 allyltriphenylphosphonium bromide 

Downstream Products

• 1234489-92-9 (3R)-(E)-6,6-diisopropyl-3-methyl-1-phenyl-6-(trimethylsiloxy)hex-1-en-4-yne 
• 1234489-93-0 (3S)-(E)-6,6-diisopropyl-3-methyl-1-phenyl-6-(trimethylsiloxy)hex-1-en-4-yne 
• 1234489-94-1 C₂₄H₄₈O₂Si₂ 
• 732248-53-2 (2S,3Z)-4-phenylbut-3-ene-1,2-diol 
• 1638238-62-6 2-phenyl-1-tosyl-6-(3-(trifluoromethyl)phenyl)-2,5-dihydro-1H-azepine 
• 1638238-61-5 6-(4-fluorophenyl)-2-phenyl-1-tosyl-2,5-dihydro-1H-azepine 
• 1638238-60-4 6-(4-(tert-butyl)phenyl)-2-phenyl-1-tosyl-2,5-dihydro-1H-azepine 
• 1638238-51-3 2,6-diphenyl-1-tosyl-2,5-dihydro-1H-azepine 
• 1638238-63-7 (E)-4-phenyl-2-styryl-1-tosyl-2,3-dihydro-1H-pyrrole 
• 1380425-96-6 (Z)-1-methoxy-4-[1-methyl-3-phenyl-2-propen-1-yl]benzene 

Relevant articles and documents

THE INFLUENCE OF (ORGANO)METALLICS "METAL-TUNING" ON STEREO- AND REGIO-CHEMICAL CONVERGENCE IN REACTIONS OF ALLYLIC CARBANIONS WITH ALDEHYDES

Although the reaction of heterosubstituted allylic carbanions (2) with aldehydes generally produces a mixture of the γ- and α-adducts (4 and 3), syn-3 and anti-3 can be prepared either exclusively or predominantly by the proper choice of the organometallic compound added.

Palladium-Catalyzed Asymmetric Tandem Denitrogenative Heck/Tsuji-Trost of Benzotriazoles with 1,3-Dienes

The asymmetric denitrogenative cycloaddition has emerged as a powerful tool to build chiral aza-heterocyles. However, only one example of asymmetric denitrogenative cycloaddition of benzotriazole with unsaturated hydrocarbons has been explored so far, bec

Enantioselective Addition of Pyrazoles to Dienes**

We report the first enantioselective addition of pyrazoles to 1,3-dienes. Secondary and tertiary allylic pyrazoles can be generated with excellent regioselectivity. Mechanistic studies support a pathway distinct from previous hydroaminations: a Pd0-catalyzed ligand-to-ligand hydrogen transfer (LLHT). This hydroamination tolerates a range of functional groups and advances the field of diene hydrofunctionalization.

Cu-Catalyzed highly regioselective 1,2-hydrocarboxylation of 1,3-dienes with CO2

A practical copper-catalyzed highly regioselective 1,2-hydrocarboxylation of terminal 1,3-diene with carbon dioxide has been developed. Under mild reaction conditions, this chemistry afforded 2-benzyl-β,γ-unsaturated acid derivatives as products, which are a kind of important unit for bio-active molecules and versatile precursors for organic synthesis, with good functional group tolerance. The key intermediate in this transformation is illustrated by control experiments.