31919-47-8

Basic information

• Product Name: 1-ADAMANTYL(PHENYL)METHANONE
• Synonyms: 1-ADAMANTYL(PHENYL)METHANONE;IFLAB-BB F0020-1589;(ADAMANTAN-1-YL)PHENYLMETHANONE;Methanone, phenyltricyclo[3.3.1.1(3,7)]dec-1-yl-;Nsc169022;((3r,5r,7r)-adamantan-1-yl)(phenyl)methanone
• CAS NO: 31919-47-8
• Molecular Formula: C₁₇H₂₀O
• Molecular Weight: 240.34
• Mol File: 31919-47-8.mol
• Article Data: 36

Chemical Properties

• Melting Point: 49-51 °C
• Boiling Point: 355.3°C at 760 mmHg
• Flash Point: 152.5°C
• Appearance: /
• Density: 1.137g/cm³
• Vapor Pressure: 3.16E-05mmHg at 25°C
• Refractive Index: 1.594
• CAS DataBase Reference: 1-ADAMANTYL(PHENYL)METHANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ADAMANTYL(PHENYL)METHANONE(31919-47-8)
• EPA Substance Registry System: 1-ADAMANTYL(PHENYL)METHANONE(31919-47-8)

Safety Data

• Hazardous Substances Data: 31919-47-8(Hazardous Substances Data)

Usage

General Description

1-ADAMANTYL(PHENYL)METHANONE, also known as 1-adamantylbenzophenone, is a chemical compound with a molecular formula C29H32O. It is a white, crystalline solid with a molecular weight of 396.57 g/mol. 1-ADAMANTYL(PHENYL)METHANONE is commonly used as a photoinitiator in the production of polymers and plastics, where it undergoes a photochemical reaction when exposed to ultraviolet light, initiating the polymerization process. It is also used as a building block in organic synthesis and can be found in some sunscreen formulations for its UV-absorbing properties. 1-ADAMANTYL(PHENYL)METHANONE is considered to be relatively stable under normal conditions, but should be handled and stored with care due to its potential for phototoxicity and irritation to the skin and eyes.

InChI:InChI=1/C17H20O/c18-16(15-4-2-1-3-5-15)17-9-12-6-13(10-17)8-14(7-12)11-17/h1-5,12-14H,6-11H2

Upstream product

• 591-51-5 phenyllithium 
• 22508-51-6 (1-pyrrolidinyl)(tricyclo[3.3.1.1^3,7]dec-1-yl)methanone 
• 180515-91-7 (1-adamantyl)diazophenylmethane 
• 110-82-7 cyclohexane 
• 100-42-5 styrene 
• 100-52-7 benzaldehyde 
• 118334-83-1 1,3-dioxoisoindolin-2-yl (3r,5r,7r)-adamantane-1- carboxylate 
• 770-71-8 1-adamantanemethanol 
• 17763-67-6 Phenyl triflate 
• 122715-82-6 S-ethyl 1-adamantylcarboxylic acid thioester 
• 768-90-1 1-Adamantyl bromide 
• 13939-06-5 molybdenum hexacarbonyl 
• 98-80-6 phenylboronic acid 
• 768-93-4 1-iodoadamantane 

Downstream Products

• 38943-55-4 2-Ethoxycarbonyl-1-adamant-1-yl-1-phenylethanol 
• 1359877-34-1 1-adamantyl-(4-aminophenyl)methanone 
• 1359877-36-3 1-adamantyl-(3-aminophenyl)methanone 
• 1207682-35-6 C₁₇H₁₉NO₃ 
• 1207682-36-7 C₁₇H₁₉NO₃ 
• 1245928-26-0 1-adamantyl-(4-nitrophenyl)methanol 
• 1359877-41-0 1-adamantyl-(3-nitrophenyl)methanol 
• 1359877-44-3 4-[1-adamantyl(methoxy)methyl]anilinium chloride 
• 1360051-02-0 4-[1-adamantyl(methoxy)methyl]aniline 
• 1359877-46-5 1-adamantyl-(3-aminophenyl)methanol 
• 1245928-25-9 1-adamantyl-(4-aminophenyl)methanol 
• 1359877-50-1 2-(1-adamantyl)-2-(3-nitrophenyl)-1,3-dithiane 
• 1359877-53-4 2-(1-adamantyl)-2-(4-nitrophenyl)-1,3-dithiane 
• 1359877-57-8 2-(1-adamantyl)-2-(4-nitrophenyl)-1,3-dithiolane 

Relevant articles and documents

Direct formation of organomanganese bromides using Rieke manganese

The direct formation of organomanganese bromides can be accomplished under mild conditions from the direct oxidative addition to Rieke manganese to alkyl and thienyl bromides.

Photoelimination of Nitrogen from Diazoalkanes: Involvement of Higher Excited Singlet States in the Carbene Formation

Although diazoalkanes are important carbene precursors in organic synthesis, a comprehensive mechanism of photochemical formation of carbenes from diazoalkanes has not been proposed. Synergies of experiments and computations demonstrate the involvement of higher excited singlet states in the photochemistry of diazoalkanes. In all investigated diazoalkanes, excitation to S1 results in nonreactive internal conversion to S0. On the contrary, excitation to higher-lying singlet states (Sn, n > 1) drives the reaction toward a different segment of the S1/S0 conical intersection seam and results in nitrogen elimination and formation of carbenes.

Method for preparing aryl ketone based on iron-catalyzed free radical-free radical coupling reaction such as ketonic acid decarboxylation and fatty aldehyde de-carbonylation

The invention discloses a method for preparing an aryl ketone derivative based on a free radical-free radical cross-coupling reaction such as ketonic acid decarboxylation and fatty aldehyde de-carbonylation. The method comprises the following steps: reacting aryl-substituted ketonic acid with fatty aldehyde under the catalytic action of ferric triacetylacetonate to generate an aryl ketone derivative; the gram-grade reaction can be realized by the method only by using 3mol% of an iron catalyst; and the method has the advantages of no need of consumption of a large amount of a Lewis acid catalyst or a stoichiometric organic metal reagent, mild reaction conditions, one-step reaction, few by-products, wide substrate application range and scalable reaction, and overcomes the defects of large catalyst consumption, insufficient functional group tolerance, many by-products and the like in the prior art.